两种无灰型含磷硫润滑添加剂在菜籽油中摩擦学性能及膜分析.pdfVIP

理化学学报(Wuli Huaxue Xuebao) May Acta Phys. Chim. Sin., 2008, 24(5) ：799-804 799 [Article] 两种无灰型含磷/硫润滑添加剂在菜籽油中的摩擦学性能及膜分析 海兵 李 晶 於 薏 左光之 任天辉 (上海交通大学化学化工学院, 上海 200240) 摘要： 以合成的两种无灰型含磷/硫化合 为润滑添加剂, 以可生物降解的菜籽油作为基础油, 用四球机研究 了体系的抗磨减摩性能, 以X 射线光电子能谱(XPS)和X 射线吸收精细结构光谱(XANES) 所形成的摩擦膜和 热膜进行了表面分析, 并初步探讨了其润滑机理. 摩擦学研究结果表明, 两种含磷/硫化合物作为菜籽油的润滑 添加剂时, 具有良好的抗磨减摩性能. XPS 和XANES 分析结果显示, 摩擦膜和热膜主要由吸附层和反应层组 成; 在表面膜中, 磷主要以磷酸盐或焦磷酸盐等形式存在, 而硫主要以硫酸盐的形式存在. 研究结果还表明, 摩擦 热在两种不同添加剂的摩擦膜形成过程中发挥着不同的作用. 关键词： 生 降解润滑油; XPS; XANES; 摩擦膜; 热膜; 润滑机理 中图分类号： O648 Tribological Behaviors and Film Analysis of Two Ashless Phosphorus/ Sulfur Containing Additives in Rapeseed Oil MA Hai Bing LI Jing YU Yi ZUO Guang Zhi REN Tian Hui (School of Chemistry and Chemical Technology, Shanghai Jiao Tong University, Shanghai 200240, P. R. China) Abstract ： Two synthetical ashless phosphorus/sulfur containing compouds were used as additives in biodegradable rapeseed oil (RSO). Their anti wear and friction reduction performances as lubricating oil additives were evaluated using four ball tester. The chemistry of their tribofilms and thermal films was analyzed with X ray photoelectron spectroscopy (XPS) and X ray absorption near edge spectroscopy (XANES), The results showed that the two phosphorus/ sulfur containing compounds possessed rather good anti wear properties and friction reducing performances. According to the XPS and XANES analytic results, the tribofilms and thermal films generated from the additives were mainly com