FCC汽油不同馏分在P_Zn_HZSM_5上的芳构化研究_赵永华.pdfVIP

( ) 2007 6 ACT A PET R LEI SINICA (PET R LEU M PR CESSING SECTI N) 23 3 : 1001-8719(2007) 03-0096-05 FCC P-Zn/ HZSM-5 STUDIES ON AROMATIZATION OF DIFFERENT FCC NAPHTHA FRACTION OVER P-Zn/ HZSM-5 CATALYST 1 1 1 1 2 赵永华 , 王海彦 , 魏 民, 白英芝 , 曹春艳 1 1 1 1 2 ZHA Yong-hua , WANG Ha-i yan , WEI Min , BAI Ying-zhi , CA Chun-yan ( 1. , 113001; 2. , 121000) ( 1. S ch ool of P etrochemical E ngineer ing , L iaoning S hih ua Univ ersity , Fushun 113001, China; 2. College of Chemistry Ch emical T echnolog y , B oh ai University , inz hou 121000, China) : P-Zn/ HZSM-5 FCC , , , P-Zn/ HZSM-5 50~ 100e 16 h , 5. 23%79.9%, 50~ 100e , 4 h , , 20 h , , ; C 9+ : P-Zn/ HZSM-5; ; ; : T E624.9 : A Abstract: T hereaction performance of P-Zn/ HZSM-5 catalyst for the aromatization of different FCC naphtha fractions was investigated on a series fixed bed reactor, and the effect of feedstock on the aromatization was discussed. T he results showed that the activity and stability of P-Zn/ HZSM-5 catalyst for the aromatization of 50- 100 e fraction were high in definite reaction conditions. After 16 h reaction, the content of olefin and aromatics in liquid product were 5. 23% and 79.9% , respectively. T he gasoline blend product of low olefin and high aromatics was obtained at last. T he distribution of benzene, toluene and xylene contents in liquid product of 50- 100e fraction changed duri