金属表面氧化法表征高阻隔特性液晶聚合物膜透氧性.pdfVIP

1 金属表面氧化法表征高阻隔特性液晶聚合物膜的透氧性 王明乐, 吴晓华, 刘剑 ( , 62 1010) : 利用原位掠入射 X 射线衍射( GIXRD) 方法和显微观察法, 研究了涂液晶聚 物膜的金属表面氧化腐蚀 情况, 根据金属表面的氧化速度计算了聚 物膜的氧气渗透性能实验测得金属表面GIXRD 衍射峰强度随 氧化时间的延长不断减弱在X 射线入射深度内, 利用显微镜原位观察得到了金属表面氧化物的面积, 结 - 2 3 2 X 射线能谱仪( EDS) 测得的氧化物中氧含量, 得到液晶聚 物膜的氧气渗透率在 10 cm / ( m d) 数量级 : 掠入射X 射线衍射; 液晶聚 物; 阻隔性; 渗透率 : T B484. 3; T B487 : A : 1001- 3563( 20 10) 11- 000 1- 05 Characterization of Oxygen Permeability of Liquid Crystal Polymer Film with High Barrier Properties by Ferrous Matrix urfaceOxidation WA N G M i ng l e, W U X i aoh ua, LI U J i an ( S uthwest University f Science and T echn l gy, Mianyang 621010, China) Abstract: This paper ut ilized insit u grazing incidence Xray diffracti n ( GIXRD) meth d and micr sc pic meth d, st udied the xidati n c rr si n n the metal surface c ated w ith liquid cry stal p lymer film, and calculated the xygen permeati n perf rmance f p lymer film acc rding t the x idati n rate n the metal surface. It w as measured by test that the diffracti n peak intensity f GIX RD n the metal surface was incessant ly w eakened with the pr l nging f x idati n time. The area f x ide n the metal surface w as rec rded by insitu ptical mi cr sc pe bservati n w ithin the incidence depth f Xray. C mbined w ith the xygen c ntent in the x ide meas ured by Xray energy dispersive spectr meter ( EDS) , the permeabilit y rate f xygen f liquid crystal p lymer - 2 3 2 film w as at the magnitude rder f 10 cm / ( m d) . Key words: grazing incidence Xray diffracti n; liquid crystal p lymer ; barrier pr perties; permeabilit y rat e , , [ 1- 3] , , , , [ 5- 7] ,