生物酶催化聚合研究进展.pdfVIP

生物技术通报 # # BIOTE CHN OLOG Y BULLET IN 2010 4 1 1 1 1 1 2 1 1 2 陕西科技大学资源与环境学院, 西安 710021; 陕西科技大学材料科学与工程学院, 西安 710021 : , 。 , HRP 、 SBP laccase 、 。 : R esear ch P rogr ess of th e En zym at ic P olym er iza tion 1 1 1 1 1 2 1 MaYanfen Lv Shenghua LiuGang ongLingxiao LiFang Wang Fei ZhengXinjian 1 2 College of Resource and Environm ent, Shaanxi Un iversity of Scien ce Techn ology, X i. an 710021; College of Ma terials Science and Engineering, Shaanxi Un iversity of Scien ce Techn ology, X i. an 710021 Ab s tra c:t Enzyme2catalyzed polymerization is one of the research focus in recent years, and oxidoreductases have showed that wide applications in catalytic synthesisofpolymer. This paper described the research progress ofenzyme2catalyzed polymerization in re2 cent years, andmainlydiscussed that the structure, catalyticmechanism ofhorseradish peroxidase, soybean peroxidase and laccase, as well as their application situation in enzyme2 catalyzed polymerization. K ey w ord s: Enzyme catalysis Horseradish peroxidase Soybean peroxidase Laccase 酶是由生物体细胞产生的一种生物催化剂,其 用情况。 本质是具有三维空间构象的一类蛋白质。酶催化具 1 [1] 有高效、专一、活性可控、反应条件温和等特点 。 辣根过氧化物酶 horseradish peroxidase, HRP 酶催化反应一般在水介质中进行, 认为有机溶剂会 是商品化较早、应用最广泛的一种酶制剂,该酶是从 [ 2] 使酶失活。1985年, Klibano