聚乙烯树脂结构对其流延基膜硬弹性与研究影响.docVIP

学号： 0 常 州 大 学 毕业论文(2013届) 题 目 学 生 学 院 材料科学与工程 专业班级 高分子0 校内指导教师 俞强 专业技术职务 教授 二○一年六月 摘 要：单向拉伸工艺是制备聚烯的主要方法，具有硬弹性结构的基膜材料是单向拉伸工艺制备微孔膜的关键步骤。。聚烯树脂结构基膜硬弹性展开研究。PE流延基膜硬弹性的影响。结果发现，高分子量的HDPE在流延过程中容易形成较多的结晶成核点，在流延辊上冷却结晶时更容易形成串行排列的片晶结构。。当基膜经过热处理之后，晶区的取向程度结晶度明显增加其硬弹性结构表现更为完善使基膜沿纵向的拉伸强度弹性模量得到一定程度的提高，并且弹性回复率也相应的提高了。。 关键词：聚烯膜；； Influence of Polyethylene Resin Structures on Hard Elastic Behavior of Their Cast Films Abstract: Uniaxial stretching process is one of the main methods of preparing polypropylene microporous membranes. Preparing cast films with hard elastic behavior is key to obtain microporous membranes by uniaxial stretching process. And polyethylene resin structures have great influence on hard elastic structures and properties of their cast films. This paper was mainly about the relationship between different PE resin chain structures and hard elastic behavior of their corresponding cast films. The influence of different molecular weights, crystallization behavior and branched chain structures on hard elastic behavior of PE cast films was investigated. It was found that PE resins with high molecular weight had more nucleating sites and row-nucleated lamellar crystallization when being cast into films, and it resulted in better hard elastic properties. In a certain draw ratio, resins with different crystallization behavior leaded to different hard elastic behavior, and those with better crystallization properties, corresponding cast films had better hard elastic behavior. Adding LDPE to HDPE resin, the crystal orientation of cast films was improved while the crystallinity and lamellae thickness decreased. This reduced the hard elastic properties of cast films, but their mechanical properties enhanced. Adding LLDPE to HDPE resin, although the crystal orientation and crystallinity of cast films decreased, the hard elastic properties of films were still unchanged and their mechanical p