Co改性Pd_C催化剂在转移加氢中应用的研究.pdfVIP

第24 卷第2 期 高 校 化 学 工 程 学 报 No.2 Vol.24 2010 年 4 月 Journal of Chemical Engineering of Chinese Universities Apr . 2010 文章编号：1003-9015(2010)02-0358-06 Co 改性的Pd/C 催化剂在转移加氢中的应用研究 郑纯智, 张国华, 文颖频, 张春勇 (江苏技术师范学院 化学化工学院, 江苏 常州 213001) 摘 要：通过调整 Co 和 Pd 的浸渍顺序制备了不同的钴改性的 Pd/C 催化剂，考察了催化剂在 3,5-二羟基苯甲酸转移 加氢制备 3,5-二氧代环己烷羧酸反应中的活性。确认先浸渍钴后浸渍钯、并在 300℃以氢气还原得到的 Co-Pd/C 催化 剂具有最佳活性，反应转化率和选择性分别达到 94.6%和 99.5% 。对该催化剂以BET 、TPR 、XRD 、SEM、TEM 、XPS 等手段进行了表征。结果表明，先浸渍的钴占据了活性炭的微孔使最可几孔径由 2.72 nm 增大为 3.32 nm，并且与一些 对反应不利的官能团作用，使后浸渍的钯主要分布在催化剂的大孔中，避免了过多深度加氢副产物的生成。催化剂活 性组分为零价的钯，其平均粒径约 10 nm，以有利于转移加氢的聚集态存在，使催化剂获得了较高的活性和选择性。 关键词：钴；Pd/C ；催化剂；3,5-二羟基苯甲酸；转移加氢 中图分类号：0643.3 ；TQ426.64 文献标识码：A Cobalt Modified Pd/C Catalyst for Tansfer Hydrogenation ZHENG Chun-zhi, ZHANG Guo-hua, WEN Ying-pin, ZHANG Chun-yong (College of Chemistry ＆ Chemical Engineering, Jiangsu Teachers University of Technology, Changzhou 213001, China) Abstract: Different cobalt-modified Pd/C (Co-Pd/C) catalysts were prepared by adjusting impregnation order of Co and Pd. The activities of these catalysts were investigated through the transfer hydrogenation of 3,5-dihydroxybenzoic acid to 3,5-dioxocyclohexane carboxylic acid. The results show that the catalyst prepared by impregnating firstly with Co then following with Pd provides the best activity, and this catalyst needs to be reduced with hydrogen at 300 ℃ before using. The conversion ratio and selectivity of this catalyst can reach 94.6% and 99.5%, respectively. The Co-Pd/C catalysts were characterized by BET, TPR, XRD, SEM, TEM and XPS, respectively. The results indicate that th