八甲基环四硅氧烷_正硅酸乙酯乳液开环聚合反应动力学.pdfVIP

# 178# PETROCHEM ICA L TECHNOLOGY 20 10 39 2 / 闫 溥, 宋秋生, 费 彬, 张玉虎 ( , 230009) [] ( D ) ( TEO S), 4 ( SDB S) TEOS , ( 5 m in) , ; ( 80 e )( 125. 2mm l/L ) SDB S ( 77. 3mm l/L ); TEOS , , 0. 42 SDB S 0. 38 TEOS ( D ) 0. 27 , 14. 67 kJ/m l 4 [] ; ; ; ; [] 1000- 8144 ( 2010) 02 - 0178- 06 [ ] TQ 311 [] A Kinetics of Emulsion Polymerization of Octam ethylcyclotetrasiloxane/Tetraethylorthosilicate Yan Pu, S ng Q iusheng, Fei Bin, Zhang Yuhu ( Sch l f Chem ical Eng ineering, H efeiUn iversity f Techn l gy, H efeiA nhui 230009, Ch ina) [ Abstract ] Cured p lysil x ane w as prepared thr ugh emu lsi n c p lymer izati n f ctam ethylcycl tetrasil xane ( D ) and tetraethyl rth silicate ( TEO S ) . The influences f pre- 4 emu lsificati n tmi e, su lfuric acid cataly st c ncentrati n, s dium d decylbenzene su lf nate emu lsifier c ncentrati n, reacti n tem perature and mass rati f TEO S t D4 n the c p lym erizati n k inetics w ere investigated. Results sh w ed that the final c nversi n f D /TEO S increased w hen pre- 4 emu lsificati n tmi e increased, and the c p lym erizati n rate w as pr m ted w hen reacti n temperature r se and the c ncen trati ns f the cataly st and em ulsifier increased. Op tmi al reacti n c nditi ns w ere pre-emu lsificati n tmi e 5 m in, c p lymerizati n temperature 80 e , catalyst c ncentrati n 125. 2 mm l/L and em ulsifier c ncen trati n 77. 3 mm l/L. The c p lymerizati n accelerated w h