催化裂化油浆富芳分中间相沥青流变性.pdfVIP

2008年 第 32卷 中国石油大学学报( 自然科学版) Vol. 32 No. 4 第 4期 Journ l ofCh in Un iversity of Petroleum Aug. 2008 : 167325005( 2008) 0420 142206 催化裂化油浆富芳分中间相沥青的流变性 李学军, 郭燕生, 程相林, 杨小军, 侯宝花, 查庆芳 (中国石油大学 重质油国家重点实验室, 山东 东营 257061) : 为了获得优质针状焦, 考察了两种中间相沥青 组织结构与流变性 关系, 以及二者 偏光显微组织结构、晶 格参数、非牛顿指数、粘流活化能 变化。结果表明: 中间相 组织结构和晶格参数与剪切应力间互为因果关系; 广 域流线性结构、晶体颗粒大且易于择优取向 中间相沥青, 其温度敏感性强, 温度平稳流动区宽, 剪切降粘效果显 著; 相比催化裂化油浆, 催化裂化油浆富芳分制备 中间相沥青流变性更好, 更有利于制备针状焦。 : 流变性; 催化裂化油浆; 针状焦; 沥青 : TE 626. 86 : A Rheological prop erties ofm esophase pitch der ived from arom atics enr iched fraction of catalytic cracking slurry LIXue2jun, GUO Y n2sheng, CHENG X i ng2lin, YANG X i o2jun, HOU B o2hu , ZHA Qing2f ng (StateKey Laboratory ofHeavyOilProcessing inChina University ofP etroleum, Dongying 257061, Shandong Province, China) Abstract: In order to get need le coke, the rel tions between textures nd rheologic l properties of both m esoph se p itches were investig ted. The ch nges in pol rized light m icro2textures, cryst l l ttice p r meters, non2Newton i n exponent swell s ctiv tion energy of viscous flow were stud ied. The resu lts show th t there were c us l rel tionsh ips bewt een textures nd l ttice p r m eters nd she r stresses. Them esoph se pitch, w ith optic lly co rse fibrous texture nd l rge cryst l s ize swell s e sily ordering, w s ofh igh temper ture sens itivity, wide temper tu re scope of sm ooth flow, nd rem rk ble she r ing d ilu2 tion. As comp red w ith FCC slurry, m esoph se p itch prep red from FCCRF slurry h s better rheologic l properties, wh ich wou ld dv nt ge to form needle coke. K ey word s: rheologic l property; c t lytic cr ck ing slurry; need le coke; pitch 在针状焦 成型过程中, 中