碱性介质中对苯二胺在铂微电极上电化学聚合的研究_百替生物.pdfVIP

碱性介质中对苯二胺在铂微电极上的电化学聚合研究 滕凯玲，葛小芳* （绍兴市环境监测中心站，绍兴，312000） 摘要：采用循环伏安法，比较了酸性、中性和碱性介质下对苯二胺（p-PD）在铂微电极上的电化学聚 合的异同，并探讨扫描速度、底物浓度等因素对p-PD在碱性体系下的电化学聚合行为的影响。结果表 明，只有碱性介质才能得到吸附于电极的高分子膜；铂电极上p-PD的氧化反应为不可逆过程；在20~100 mV/s的扫描速率范围内，阳极峰电流与扫描速度的1/2次方成线性关系，表明该电极反应受扩散控制。 关键词：碱性介质；电化学聚合；循环伏安法；对苯二胺 ElectrochemicalPolymerizationofp-PhenylenediamineonPt ElectrochemicalPolymerizationofp-PhenylenediamineonPt EElleeccttrroocchheemmiiccaallPPoollyymmeerriizzaattiioonnooffpp--PPhheennyylleenneeddiiaammiinneeoonnPPtt Microelectrode inAlkaliMedium Microelectrode inAlkaliMedium MMiiccrrooeelleeccttrrooddeeiinnAAllkkaalliiMMeeddiiuumm Tekailing, Ge Xiaofang (ShaoxingEnvironmental Monitoring Center Station, Shaoxing, 312000) Abstract: Abstract: AAbbssttrraacctt:: The electrochemical behavior of p-phenylenediamine (p-PD) on Pt microelectrode in different aqueous medium was studied by cyclic voltammetry technique, and the effects of scan rate and reactant concentration on electrochemical characteristics ofp-phenylenediamine inalkaline medium were investigated systematically. The results showed that p-PD could be electrochemically polymerized in alkaline aqueous solution. The oxidation of p-PD on Pt microelectrode was an irreversible process, and anodic peak currents depended linearly on the square root of scan rate over the range of 20~100 mV/s, which suggested that the process ofthe electrode reaction was controlled bythe diffusion. Keywords: Keywords: KKeeyywwoorrddss::Alkali medium, Electrochemical polymerization, Cyclicvoltammetry,p-Phenylenediamine 作者简介：葛小芳(1978-)，女，浙江诸暨人，助理工程师，硕士，主要从事环境监测和环境管理工作。 1 1 11 前言 [1] [2] 聚苯二胺类电活性高分子由于其在防腐、电致变色器件 、电催化 、分子印迹型化 [3]