交流阻抗模拟软件应用Zview.pptVIP

Analysis of electrochemical impedance spectra (EIS) Reporter: LingChen Mar. 3rd 2006 Introduction of EIS Electrochemical impedance spectroscopy (EIS) is a very powerful tool to analyze the electrochemical electrode reactions and has been commonly used to analyze the electrochemical interface. Impedance spectrums are often modeled using an electrical circuit which produces a similar spectrum. The electrical components (resistors, capacitors, inductors, etc) and some components that have no electrical analog (constant phase elements, Warburg impedances, etc) are then matched to physical characteristics of the measured cell. Outline 1.Fit by Zview Software 2.Data preparation 3.Examples One method of producing initial values 1.4 Examples Example 1 Example 2 2.1 Experiment results 2.2 Data Transformation Example Summarization We must rely on our own knowledge of the physical system we are measuring. It can also be helpful to see if the model gives “reasonable” values. Real experimental data is usually harder to model so we need take our time and work our way to finally fitting the data. Thanks! * * * * * 1. Fit by Zview 1.1 Circle Fit The semi-circle fit is a geometric fit not an RC or Equivalent Circuit fit. 1. Fit by Zview 1.2 Instant Fit CPE = Constant Phase Element Parameters: CPE-T, CPE-P Z = 1 / [T(i×ω)P] CPE-P = 0.5 a 45 degree line CPE-P = 1 a capacitor Often a CPE is used in a model in place of a capacitor to compensate for non-homogeneity in the system. 1. Fit by Zview 1.3 Equivalent Circuits Fit Z’ ~ Z’’ f ~ p f ~ Z 2.Data preparation -9.09017 4.05871 -0.64123 4.00774 76095 … … … … … -6.17213 3.9419 -0.42382 3.91905 100000 -3.31484 1151.56 -66.5861 1149.63 0.01314 -0.85309 1170.64 -78.6652 1167.99 0.01 - + - + + phase IZI Z’’ (imaginary) Z’ (Real) Frequency (Hz) The data is transformed to ASCII form by Origin software 2.Data preparation * * *