锂二次电池石墨负极SEI生长过程.pdfVIP

Technical Report 報　文 リチウムイオン二次電池用グラファイト負極上の SEI 被膜の成長過程 Growth Process of SEI Film on Graphite Negative Electrode for Lithium-ion Secondary Battery ＊ ＊ ＊ 田　尾　洋　平 　　山　手　茂　樹 　　尾　崎　哲　也 ＊ ＊ ＊＊ 稲　益　徳　雄 　　吉　田　浩　明 　　奥　山　良　一 Yohei Tao　　Shigeki Yamate　　Tetsuya Ozaki Tokuo Inamasu　　Hiroaki Yoshida　　Ryoichi Okuyama Abstract The film containing the solid electrolyte interface (SEI) formed on the graphite negative electrode of a lithium-ion secondary battery (LIB) has been investigated to demonstrate the theoretical model of the well-known life predic- tion method for the LIB, so-called “square root law”. This theoretical model is based on the assumption that the thickness of the SEI film is proportional to square root of testing time (SQRT). In order to verify the assumption, these thicknesses have been observed by using the in-lens scanning electron microscopy. Each of the thickness of the SEI film at different point of the negative electrode is proportional to SQRT. Then, the amount of Li accumula- tion in the film has been quantified by using the inductively coupled plasma atomic emission spectroscopy. It is also proportional to SQRT. Furthermore, the amount of Li in the SEI film volume has been estimated from these re- sults. It is almost constant and remains unchanged throughout the charge/discharge cycle test. These results indi- cate the validity of the assumption for “square root law” in the pra