【英文】对称聚(苯乙烯- 块 -丁二烯- 块 -甲基丙烯酸甲酯)表面重构.pdfVIP

7502 Macromolecules 1996, 29, Surface Reconstruction of the Lamellar Morphology in a Symmetric Poly(styrene-block-butadiene-block-methyl methacrylate) Triblock Copolymer: A Tapping Mode Scanning Force Microscope Study Wolfgang Stocker,*,† Jo rg Beckmann,‡,§ Reimund Stadler,‡ and Ju rgen P. Rabe† Institut fu¨ r Physik, Physik von Makromoleku¨ len, Humboldt Universita¨t zu Berlin, Invalidenstrasse 110, D-10115 Berlin, Germany, and Institut fu¨ r Organische Chemie, Johannes Gutenberg Universita¨t Mainz, J. J. Becherweg 18-20, D-55099 Mainz, Germany Received March 14, 1996; Revised Manuscript Received August 3, 1996 ABSTRACT: The surface morphology of a symmetric poly(styrene-block-butadiene-block-methyl meth- acrylate) triblock copolymer (PS-b-PB-b-PMMA) with 6 wt % PB has been investigated by tapping mode scanning force microscopy (SFM). The results are compared to the bulk morphology as determined by transmission electron microscopy (TEM). In solvent-cast films PS/PMMA lamellae are formed, which are oriented nearly perpendicular to the free surface. Like in the bulk, also at the free film surface polybutadiene spheres are located at the lamellar PS/PMMA interface. However, contrary to the bulk, the surface morphology includes a large number of defects such as curved lamellar and disclinations, and the lamellar long period is doubled,