水溶性金属卟啉应用于催化反应研究进展.pdfVIP

2010 年第 30 卷 有 机 化 学 Vol. 30, 2010 第 11 期, 1605～1614 Chinese Journal of Organic Chemistry No. 11, 1605～1614 ·综述与进展· 水溶性金属卟啉应用于催化反应的研究进展 任清刚 周贤太 纪红兵* ( 中山大学化学与化学工程学院 广州 510275) 摘要 综述了水溶性金属卟啉作为催化剂应用于均相或非均相的催化反应的研究进展, 重点介绍了水溶性金属卟啉在 水或水与有机溶剂混合介质中催化底物氧化反应的催化性能, 其中包括烷烃的羟基化, 烯烃的环氧化, 含氧、含硫及含 氮化合物的氧化反应. 另外水溶性金属卟啉还可用于催化 Suzuki-Miyaura 反应、氧化偶联反应、C ＝C 氧化断裂反应等. 水溶性金属卟啉催化剂具有水溶性、催化效率高、反应条件温和等优点, 因此将在催化反应特别是氧化反应中得到更 广泛的应用. 关键词 水溶性金属卟啉; 催化氧化; 仿生催化 Progress of Water-Soluble Metalloporphyrins in Catalytic Reactions Ren, Qinggang Zhou, Xiantai Ji, Hongbing* (School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275) Abstract The latest applications of water-soluble metalloporphyrins as catalysts in catalytic homogeneous or heterogeneous reactions are reviewed, focusing on the catalytic activities of water-soluble metallopor- phyrins-catalyzed oxidation reactions in water or the mixed media of water and organic solvents, including the oxidation of alkanes, epoxidation of alkenes, the oxidation of compounds containing oxygen, sulfur and nitrogen. Water-soluble metalloporphyrins could also be used in other catalytic reactions, such as Su- zuki-Miyaura reaction, oxidative coupling reaction, oxidative cleavage of C ＝C double bond etc. Wa- ter-soluble metalloporphyrins as catalysts will be widely used in catalytic reactions, especially in oxidations for its water solubility, effective activity, and under mild conditions. Keywords water-soluble metalloporphyrin; cata