镉污染源水的应急处理技术研究.pdfVIP

25 11 Vo.l 25 No. 11 2009 6 CHINA WATER WASTEWATER Jun. 2009 1 2 2 1 1 1 高中方, 周克梅 , 陈志平 , 陈 卫, 林 涛 , 王 旭 ( 1. 河海大学 环境科学与工程学院, 江苏 南京 210098; 2.南京市自 水总公司, 江苏 南京 210002) : 分析了发生突发性镉污染时镉在水体中的存在形式,考察了常规混凝化学沉淀以 及两者联用对镉污染源水的处理效果结果表明: 发生突发性镉污染时,镉在水体中主要以溶解态 形式存在,所占比例 60% ; 常规混凝沉淀可有效去除吸附态镉,但对溶解态镉的去除效果有限; 化 学沉淀法对镉有良好的去除效果,但会增加滤后水的浊度; 化学沉淀与混凝联用技术可大大提高对 镉的去除效果,在预调 pH 值至 10PAC的投加量为 20mg/L时, 对镉的去除率 97. 7%, 最大可处 理浓度提高至 0. 220~ 0. 264mg/L : 突发性镉污染; 应急处理; 混凝沉淀; 化学沉淀; 联用 : TU991 : C : 1000- 4602( 2009) 11- 0086- 03 Study on Em ergency T reatm en t Technology of SourceW ater Pollu ted by Cadm ium 1 2 2 1 1 GA Zhongfang, ZH U Kemei, CHEN Zhiping , CHEN Wei, LIN Tao, 1 WANG Xu ( 1. College of Environm entalScience and Eng ineering, H ohai University, N anj ing 210098, China; 2N anj ing Tap Water eneral Company, N anjing 210002, China) Abs tract: The existing forms of cadm ium (Cd) in water polluted accidentally by Cd were ana lyzed, and the removal effects of Cd by conventional coagulationsedmi entation, chem ical precipitation and the combined process were investigated. The results show that the dissolved Cd accounts for above 60% of the total Cd under accidental Cd pollution. The adsorbed Cd can be removed efficiently by the conventional coagulationsedmi entation, while the removal efficiency of the dissolved Cd is poor. The