有机磷酸酯金属配合物的合成及表征.pdfVIP

# # # # # # # # # # # # # # # # # # # # # # # # # # # # # # # # # # # # # 2010 3# 27# 3( )# # # # # # HEN N CHEM IC L INDU STRY ∀ 59∀ (,, , 461000) 2, 2- - 1, 3- () 5, 5- - 1, 3- (), , 5, 5- - 1, 3, 2- , 5, 5- - 1, 3, 2- 1, 10- ( CuZnCoN i), IR ; 5, 5- - 1, 3, 2- ; S143. 2+ 4 B 1003- 3467( 2010) 06- 0059- 02 1 HCl(, 1. 1 ), 1%, 4/5 2. 4. 2 5, 5- - 1, 3, 2- , (: 9. 2 g, 60mL( 1: ) 1) 250mL, , 15, , , , ,, , 12. 2 g, 74. 5%, m. p. 171~ 173! , ; ( 2) 2. 4. 3 Cu 0. 050 g ( 0. 25 mmol) : 5, 5-- 1, 3, 2- Cu( O c) ∀ H O, 0. 0496 g( 0. 25 mmol) 1, 10- 2 2 , 0. 083 g( 0. 5mmol) 5, 5- - 1, 3, 2- ( ), IR 50mL, 30 mL , 1. 2 , , 15 m in, , , , 5, 5- , 20 mL / ( 1: - 1, 3, 2-, 5, 5- - 1, 3, 2- 1), 50mL , , , ( CuZnCoN i) 2. 4. 4 N i 0. 0622 g( 0. 25 mmol)N i ( O c) ∀ 4H O, 0. 083 g( 0. 5mmol) 5, 5- - 1, 3, 2 2 2 2 2. 1 - , 0. 0496 g( 0. 25 mmol) 1, 10- 50mL, 30 mL, , 15m in, , 5. 0mL, 50 mL , , ,