气相色谱双柱法测定果汁中多种有机磷类农药残留量.pdfVIP

1902010,V01．31，No．04 食晶科学 ※分析枪测 气相色谱双柱法测定果汁中多种 有机磷类农药残留量 高巍，卢剑，武中平，耿宁 (江苏省产品质量监督枪验研究院，江苏南京 210029) 摘要：采用气相色谱双柱法对果汁中多种有机磷类农药残留量进行测定。样品用丙酮提取后，经Carb／NH2同相 萃取小柱净化，用DB一1701、DB．35ms毛细管气相色谱柱，火焰光度检测器，对果汁中多种有机磷类农药残留量 的测定可取得满意的结果。该方法测定样品的平均加标回收率为75．23％～98．53％，相对标准偏差为O．97％～ 8．16％，果汁中自‘机磷类农药残留检出限为10～60“gg。 关键词：果汁；有机磷类农药；残留最；气相色谱双柱法；火焰光度检测器 Multi-residuesinFruitJuice Dual—columnGas of Pesticide ChromatographicAnalysisOrganophosphoms GAOWei，LUJian，WU Zhong—ping，GENGNing Provincial and ResearchInstituteforProducts 210029，China) (Jiangsu SupervisingTesting Quality，Nanjing Abstract：Adual-column methodwas forthemulti—residuedetermination developed gaschromatographic in with the extractwas OnCarb／NH2SPE weldextracted cleamed pesticidesfruitjuice．Samples acetone，andmsdting up c锄idge． DB．1701and weredetectedwithFPD． The wasachievedon DB一35ms chromato粤aphicseparation capillarycolumns．Analytes bet、僦n The recoveriesof6 for inblank at3levels 75．23％and98．53％．with samples average replicatesanalytes spiked ranged relativestandarddeviationsbe相，a％0．97％and8．16％．Thelimitsofdetectionwcrewithinthe of range10—60“eCkg． words：fruit column pesticides；multi-residues：dualgaschromatography；FPD Key ju