Solutions to Exercises-Chapter 5-化学平衡原理.docVIP

Solutions to Excercises Chapter 5 化学平衡原理 Ⅰ. ?Fill in the blanks 1. For the reaction: 2HgO(s) == 2Hg(l) + O2(g), its expression of standard equilibrium constant, , is , the unit of is ; The expression of experimental equilibrium constant, , of the reaction is , the unit of is . (, 1, , atm or kpa) 2. For the gaseous equilibrium at a given temperature: PCl5(g) == PCl3(g) + Cl2(g), a endothermic reaction, when we increase the temperature of system the reaction shift to the ; when we increase the pressure of the system the reaction shift to the ; when we increase the concentration of PCl5 the reaction shift to the ; when we decrease the partial pressure of chlorine gas the reaction shift to the ; when we apply a catalyst to the reaction, it will accelerate both forward and backward reactions , but the equilibrium constant of the reaction will . ( right, left, right, right, equally, not change) Ⅱ. Multiple Choice (only one is correct) (b)1. Given the equilibrium constants at 25℃ for the following two reactions H2(g)+S(s) = H2S(g) S(s) + O2(g) = SO2(g) the value for H2(g) +SO2(g) = O2 (g) +H2S (g)is calculated as (a) (b) (c) (d) (b)2. What is the relation between Kc and Kp of the following reaction? H2O(g) + CO(g)= CO2(g) + H2(g) (a) Kp=Kc(RT)-1 (b) Kp=Kc (c) Kp=Kc(RT) (d) Kc=Kp(RT)-2 (c)3. What is the equilibrium constant at 25℃ for a reaction that has ?Go = 0 kJ? (a) K 1 (b) K 1 (c) K = 1 (d) K = 0 Ⅲ. True or False (mark “T” for the correct and “F” for the wrong) (F)1. The reaction, 2C(s) + O2(g) == 2CO2(g), will be shifted to the right if we reduce the volume of the reaction system. (F)2. The equilibrium constant of a reaction at a give temperature will increase if we increase the concentration of react