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PC/ASA-Blends with Improved Low Temperature Toughness
Introduction
For many years, the automotive industry has been one of the application areas most open to innovations. Increasing demands in terms of environmental compatibility and thus lightweight construction for automobiles are the reasons for the ever-growing amount of plastics being used. In fact, plastics are even making inroads into the exterior car body parts that up to now has been the sole domain of the classic materials namely, steel and aluminium.
During the last ten years, especially impact toughened PA/PPE- and PC/PBT-alloys were used as materials for fenders, bumpers or tailgates. These materials offer excellent impact strength, but suffer from their low dimensional stability.
Blends based on amorphous components like PC and Styrenics offer a much higher dimensional stability as well as high toughness. They already have reached a sales volume of more than 300.000 t per year. In this paper we will discuss about the opportunities to use a new developed PC/ASA-blend as material for exterior car parts. Especially we will focus on the possibilities to improve the low temperature toughness of PC/ASA-blends.
Experimental Details
For the preparation of the investigated materials the following raw materials were used:
Polycarbonate (PC): Lexan 161 (General Electric Plastics)
ASA- Rubber: PSAN-grafted Acrylate-Rubber with 65 wt.-% Rubber and a particle size of the grafted rubber particles (d50) of 510 nm.
PSAN: Copolymer consisting of 80 wt.-% Styrene and 20 wt.-% Acrylonitrile
Siloxane-Rubber: Metablen?S 2001 (Elf-Atochem)
HM-PMMA: PMMA with Mw=1800000 g/mol
The blends were compounded using a twin screw extruder (ZSK 30, Werner Pfleiderer).The samples for the mechanical testing were prepared by injection moulding according to ISO-standards. The materials temperature was 260°C, the mould temperature 80°C. The mechanical testing was performed according to ISO- and DIN-procedures:
Charpy notched impac
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