糖蜜酒精厌氧出水论文：糖蜜酒精厌氧出水强化预处理技术研究.docVIP

糖蜜酒精厌氧出水论文：糖蜜酒精厌氧出水强化预处理技术研究 【中文摘要】目前,针对糖蜜酒精厌氧出水的研究较少。糖蜜酒精废水经过厌氧处理后,仍存在较高浓度的有机物(COD-14220mg/L),大多以长链烃类、烯烃类、苯类及酚类的形式存在,生物毒性大(EC50=15.21%),且BOD5/COD低(0.14),色度高(5880倍),是一种难生物降解的有机废水。针对废水有机浓度高难降解特性,本文选用Fenton氧化工艺和铁炭微电解对废水进行强化预处理,以降低废水的生物毒性,提高其可生化性(BOD5/COD)。实验首先采用单因子杯罐试验法考察Fenton氧化工艺处理,实验结果表明,在初始pH=6, m(H2O2):m(Fe2+)为1：1,H202的用量为2.13g/L,采用氢氧化钙调节出水pH值至9,COD去除率77%,色度去除率为86%,可生化性略有提高(BOD5/COD为0.24)；生物毒性由强毒降为无毒,通过GC-MS分析可知出水中几乎无大分子有机物。试验对比Fe2+ 【英文摘要】Molasses alcohol anaerobic effluent contains plenty of toxic organic compounds, such as long-chain hydrocarbon, olefin, benzene and form phenols, which leads to poor biodegradability. In order to ensure that wastewater could meet the discharge standard, pretreatment of high density and refractory organic compounds is indispensable. Therefore, experiments were conducted to study the role of Fenton reaction and micro-electrolysis in removing COD and decreasing toxicity and improving the biodegradability.Fenton treatment was preliminarily employed to investigate the mechanisms of affecting factors. Based on both of the removal performance and the operating costs, optimal reaction condition was proposed as follows:m(H2O2):m(Fe2+)=1:1, H2O2 dosage2.13g/L,30min at initial pH=6, and the treated wastewater regulated by calcium hydroxide. Under these conditions, the COD removal is 77%, color removal is 86% and the degradability of Fenton effluent can be enhanced to 0.24 (BOD5/COD), bio-toxity decreased to non-toxic from strong toxicity. Furthermore, organic compounds analyzed by GC-MS method are mainly non-toxic complex organics. Operation cost was 16.33 RMB/t considering reagent cost.Due to costliness of H2O2, further experiment of iron-carbon electrolysis was pretreated by iron-carbon micro-electrolysis and the effect of the influent pH value, iron to carbon ratio, and aeration time on the COD removal efficiency was mainly discussed. Operating at m (iron):m(carbon)=1:1, aeration time 5.5 hour at initial pH=3, and calcium hydroxide regu