全沉积型铅酸液流电池性能研究.docVIP

全沉积型铅酸液流电池性能研究( 刘旭东，毕孝国，董颖男，关新，吉晓瑞 （沈阳工程学院，沈阳 110136） 摘 要TM911 Study on Performance of Lead Acid Flow Battery LIU Xudong**, BI Xiaoguo, DONG Yingnan, GUAN Xin, JI Xiaorui (Shenyang Institute of Engineering, Shenyang 110136) Abstract The charge and discharge characteristics of a novel lead acid flow battery with a single electrolyte, lead(II) in methanesulfonic acid were studied in this paper. The effects of charge and discharge conditions and lead(II) concentrations on performance of flow battery are analyzed in detail. The results showed that the charge voltage was almost constant and the average discharge voltage and energy efficiency increased gradually with the increasing cycle numbers of charging and discharging. The discharge voltage and time decreased gradually with increasing discharge current density, and the coulomb efficiency was smaller when the discharge current density was too large or small. The flow battery had good charge and discharge performance with large current density after the cell was activated by charging and discharging with small current density. The charge voltage decreased and the discharge time at larger voltage increased with increasing lead(II) concentration, which improved the charge and discharge performance of lead acid flow battery. KEY WORDS inorganic non-metallic materials, graphite felt, nickel foam, lead acid flow battery, charge and discharge characteristics 全沉积型铅酸液流电池是基于传统铅酸蓄电池一种新液流储能电池。具有优点，铅酸液流电池的电极材料、电解液的组成与性质和电池性能国内的研究主要集中在全钒、多硫化钠/溴和铁/铬等传统液流电池体系电极材料、电解溶液与离子交换膜对电池性能的影响规律而全沉积型铅酸液与Pb2+电极的制备是将石墨毡、泡沫镍裁剪成为?10mm的试样，并将其镶嵌在尺寸为15mm×25mm×3mm的聚乙烯板基体中，以铜网为集流体、铜线为引线连接，然后以熔化的石蜡进行封·L-1、0.25mol·L-1和0.5mol·L-1，而CH3SO3H的浓度均为0.05mol·L-1。将配制好的电解液取100ml加入小烧杯中，插入上述制备的泡沫镍负电极和石墨毡正电极，组成全沉积型铅酸液流电池。采用新威尔公司的BTS-5V3A电池性能测试仪测试电池的充放电性能。测试过程中进行电磁搅拌模拟电解液的流动现象，搅拌速度为180r/min。 3 结果和讨论 3.1 电池充放电特性 图1 电池的充放电特性 Fig. 1 Charge and discharge characteristics of battery 为了分析上述铅酸液流电池的充放电特性，电池的正、负电极分别为石墨毡和泡沫镍，电解液为0.25mol·L-1Pb(CH3SO3)2+0.05mol·L-1CH3SO3H混合液，电池以3