激发剂对锰渣胶凝性能的影响.docVIP

激发剂对锰矿渣胶凝性能影响摘要Al2O3、CaO、SiO2、MnO等为主；矿物组成主要有Al2O3、SiO2等；活性检验得知其具有火山灰活性。 在选用工业石膏、明矾、明矾石的基础上，探索其对锰矿渣的活性激发效果，结果表明：500℃煅烧工业石膏、300℃煅烧明矾、550℃煅烧明矾石对锰矿渣的活性激发效果较佳。其中煅烧明矾的激发效果比煅烧石膏好。 在自配激发剂的基础上，分析其对锰矿渣的活性激发效果，结果表明:SSY具有较好的早期强度，后期强度增长缓慢；SMJ、SLJ强度稳步增长，具有较大的28d强度。 对化学活化锰矿渣水泥水化过程的XRD分析和化学结合水量测定，结果表明：随着龄期的增长，水化的深入进行，水化产物也逐渐增多，化学结合水量也逐步增多。煅烧石膏因为溶解性较高，而在一定程度上提升早期水化速度；煅烧明矾水解生成的Al3+、SO42-与锰矿渣水泥中的铝酸盐矿物迅速反应生成钙矾石，提高水泥的硬化速度Effect Of Activator On Cementing Performance Of Manganese Slag Abstract In this paper manganese slag, which is from Chichou, Guangxi, is studied. From the result of its basic properties analysis, it can be tested that principal chemical components in manganese slag are Al2O3, CaO, SiO2, and MnO. Among mineral constituent there are Al2O3,SiO2. In addition, the result from activity testing presents its volcanic reactivity. FGD gypsum, alunite, alumstone are chosen as the activators to explore on how to activate the reactivity of manganese slag. The results can approve that: calcined gypsum under 500℃, calcined alunite under 300℃, calcined alumstone under 550℃ have performed good exciting effort on manganese slag. Else, when calcined alunite added, manganese slag cement will easily gain better cementing property. On the basis of the compound activator, their exciting result can be analyzed. The results can approve that: SSY presents dual early strength effect, whereas the increasing ratio of the later strength is much slow and little. SMJ and SLJ can promote steady progress of mechanics strength, and have better strength values up to 28 days. Hydration process of activated manganese slag cement can be studied by methods such as XRD analysis and chemically combined water content test. The results can approve that: With the increasing of age, large amount of hydration product can be stepwisely generated. As a result, the chemically combined water content increases. Calcined gypsum has easier dissolution capacity, and could promote the hydration process at early age. Calcined