十二烷基硫酸钠对电沉积镍电化学行为的影响.pdfVIP

36 6 2010 12 Vol36 No6 M etal Products December2010 doi: 10. 3969/j. issn. 1003- 4226. 2010. 06. 00 王永银, 司云森, 陈 阵, 余 强 , 许 娜 ( , 650093) ( SDS), SDS, : W atts SDSW att SDS 0. 1~ 0. 2 g/L , ; SDS 0. 2 g /L , (R ct ) 2 1 029 cm ; SDS 0. 3 g/L , , R ct, SDS 0. 1~ 0. 2 g/L ; ; ; ; TQ15 E ffect of SD S on electrochem ical behavio r of electrodepo sited n ickel W ANG Y ongy in, S IY unsen, CHEN Z hen, YU Q iang, XU Na (K unm ing Un iversity of Sc ience and Tech nology, K unm ing 650093, Ch ina ) A b stract To research effect of sodium dodecyl su lfate ( SDS) on electrochem ical behavior of electrodeposited nicke.l Po larization curve and alternating curren t mi pedance spectroscopy of SDS solution electrodepos ited nickel of d ifferent m ass concen tration arem easured separately by adopting dynam ic poten tial scan and alternating current mi pedance m ethod. Re sults show that adding SDS in theW atts solution can reduce the cathode polarization. W hen the SDS m ass concentration of W atts solution is 0. 1~ 0. 2 g/L, polarization decreases little, SDS m ass concentration is 0. 2 g/L, charge passing res istance 2 can reach 1029 cm , when them ass concentration of SDS is over 0. 3 g/L, polarization decreases significantly, charge passing resistance is little, close coating is difficult to form. Them ass concentration of SDS should be controlled 0. 1~ 0. 2 g/L as trad itionalw etting agent and pinhole prevention agent. K eyw ord s electrochem ica;l nickel p lating; cathode polarization; a