粘胶活性碳纤维预浸剂的热分解作用及效能评选.pdfVIP

第22 卷 第5期 总第91期 Vol 1 2 2 No 1 5 Journal of Materials Science Engineering Oct . 2004 :1004-793X(2004)05-0688-05 , ( P, 200051) = , P , , , P, ; , , , = ; ; P; + :TQ342 .742 :A Pyrolyses of Rayon Pre-treated by Im regnants and the Evaluation of their functions for Rayon-Based Activated Carbon Fiber ZENG Fan-long, PAN Ding ( Carbon Fiber DivisionPState Key Lab. for Modification of Chemical Fiber and Polymer Materials, College of Materials, Dong Hua University, Shanghai 200051, China) = Abstract With the help of thermal gravimetric analysis (TGA) , the pyrolyses of rayon have been studied respectively by using im- pregnants phosphoric acid ( PA) , its three ammonium salts and ammonium sulfate (AS) . The air is favorable for the pyrolysis of rayon treated by dibasic ammonium phosphate ( DAP) , but useless for those of the other impregnants. It is put forward that the ratio of height to half- height-width ( HPW ) of a peak on a differential thermal gravimetric ( DTG) curve could be used to describe the peak. s shape character. 1P2 The smaller the ratio is, i. e. the more flatten the peak is , the more moderately the thermal decomposition reaction carries out , which would lead to higher carbonization and activation yields of rayon. The experimental results prove this point of view. According to expectation, DAP. s function is the best, ammonium dihydric phosphate. s (ADP) is equal to PA. s, ammonium phosphate. s(AP) is worse; AS has lower specific surface area, and no-impregnant gives the lowest yield and speci