不同结构聚醚改性硅油消泡剂的制备.pdfVIP

第31卷第5期 印染助剂 Vol.31No.5 2014年5月 TEXTILE AUXILIARIES May2014 不同结构聚醚改性硅油消泡剂的制备 窦尹辰，郭 睿，王安琪，郑淑华 （陕西科技大学，教育部轻化工助剂化学与技术重点实验室，陕西西安710021） 摘 要：以含氢硅油、烯丙醇聚醚和烯丙基聚氧乙烯聚氧丙烯甲基醚为原料,在催化剂氯铂酸作用下,合成了不同结构聚醚 改性硅油,用红外光谱、核磁共振氢谱对其结构进行表征.单因素试验结果表明:在95℃、7h、催化剂用量20μg/g条件下,Si—H转化率 可达93.6%.n(烯丙醇聚醚)∶n(烯丙基聚氧乙烯聚氧丙烯甲基醚)=4∶1时,改性硅油水溶液表面张力为28.6mN/m,浊点为24℃.将改性 硅油用作消泡剂并测试了其消泡、抑泡性能. 关键词：含氢硅油; 烯丙醇聚醚; 烯丙基聚氧乙烯聚氧丙烯甲基醚; 改性硅油; 消泡剂 中图分类号: TQ423.95 文献标识码: A 文章编号: 1004-0439(2014)05-0024-04 Preparation of polyether modified silicone defoamers with different structures DOU Yin⁃chen，GUO Rui，WANG An⁃qi，ZHENG Shu⁃hua (KeyLaboratoryofAuxiliaryChemistry ＆TechnologyforChemicalIndustry,MinistryofEducation, ShaanxiUniversityofScience ＆Technology, Xi′an 710021, China) Abstract: Different structures of polyether modified silicone defoamers were prepared by polyhydrosili⁃ cone oil, allyl alcohol polyether and allyl polyoxyethylene polyoxypropylene methylether, using chloroplatinic ac⁃ id as the catalyst. The chemical structure was characterized by infrared spectrum (IR) and proton nuclear mag⁃ netic resonance (1HNMR). The results of single factor experiments showed that under the conditions of 95 ℃, 7 h, and catalyst dosage of 20 μg/g, the Si—H conversion rate could reach 93.6%. When the molar ratio of al⁃ lyl alcohol polyether and allyl polyoxyethylene polyoxypropylene methylether was 4 ∶1, the surface tension of modified silicone oil aqueous solution was 28.6 mN/m and the cloud point achieved 24 ℃. The modified sili