水泥浆界面层的形成机理.pdfVIP

21 2 Æ Vol.21 No.2 2 0 0 7 4 CHINESE JOURNAL OF MATERIALS RESEARCH April 2 0 0 7 // ∗ ( 515063) (SCA) , (FTIR) X (XPS) SCA . , SCA , . /SCA/, SCA . , , , /SCA/, TU528 1005-3093(2007)02-0140-05 Forming mechanism of granite/silane coupling agent/cement paste interface LI Yili LU Xiaohua FENG Yulong XIONG Guangjing∗∗ (Department of Civil Engineering, Shantou University, Shantou 515063) * Supported by National Natural Science Foundation of China No Manuscript received June 19, 2006; in revised form August 30, 2006. ** To whom correspondence should be addressed, Tel:(0754)2902989, E–mail:gjxiong@stu.edu.cn ABSTRACT The mechanisms that the bond strength between aggregates and cement paste could be significantly increased by modifying the aggregate surfaces with silane coupling agent (SCA) were analysed. The formation and the influencing factors of granite/SCA interface were investigated using spectrophotometry, contact angle measurement, FTIR and XPS. The results revealed that strong bonds, including chemical bonds, formed on the modified granite surfaces. The interface transition zone (ITZ) benefits from the existence of the uncondensed silanetriols and the distributed organofunctional network. KEY WORDS inorganic non–metallic materials, concrete, silane coupling agent, granite/SCA/cement paste interfacial layer, bond mechanism 15 m3 , . Æ 40%[1]; C50 , (SCA) [2] [8] Æ 90% . Æ,