通过原位聚合的含氯阻燃聚氨酯纳米复合材料的合成与表征.pdfVIP

Synthesis and Characterization of Chlorine-Containing Flame-Retardant Polyurethane Nanocomposites via In Situ Polymerization M. Mohammadi Aslzadeh,1 G. Mir Mohamad Sadeghi,2 M. Abdouss1 1Chemistry Group, Chemical Engineering Department, Amirkabir University of Technology, 15875/4413 Tehran, Iran 2Polymer Engineering and Color Technology Department, Amirkabir University of Technology, 15875/4413 Tehran, Iran Received 11 August 2010; accepted 3 January 2011 DOI 10.1002/app.34074 Published online 28 July 2011 in Wiley Online Library (). ABSTRACT: We have developed flame-retardant polyur- ment (chlorine content) leads to the increase in flame ethanes (FRPUs) and polyurethane (PU) nanocomposites retardancy and burning time. Addition of nanoclay to via in situ polymerization. Three series of thermoplastic CPD-containing PUs leads to obtain self-extinguish PUs elastomeric PUs were synthesized to investigate the effect using lower CPD contents, higher Young’s modulus, and of incorporating 3-chloro-1,2-propanediol (CPD) and nano- strength without any noticeable decrease in elongation at clay on mechanical, thermal properties, and also resistance break. Investigation of the TGA results showed that copre- to burning. PU soft segments were based on poly(propyl- sence of nanoclay and chlorine structure in the PU back- ene glycol). Hard segments were based on either CPD or bone can change thermal degradation pattern and improve 1,4-buthane diol (BDO) in combination with methyl phe- nanocomposite thermal stability. X-ray diffraction and nyl di-isocyanate named PU or FRPU, respectively. In the transmission electron microscopy studies confirmed that