联苯氯甲基化反应的研究.pdfVIP

13 10 V ol. 13, N o. 10 2005 5 21 F ine and Specialty Chem ica ls 25 联苯氯甲基化反应的研究 1 2 1 2 2 1 方 奇 朱春燕 任晓丽 薛 璋 夏剑忠 沈永嘉 ( 1. 华东理工大学精细化工研究所, 上海 200237; 2. 上海宝 化工股份有限公司, 上海 201900) , /H2 O , , 4, 4 ; ; 4, 4; Study on Ch lorom ethylation of B iphenyl 1 2 1 2 2 1 FANG Q i , ZH U Chunyan , REN X iaoli, X UE Zhang , X IA J ianzhong , SH EN Yong j ia ( 1. In stitute o f F ine Chem ica ls, East China U niversity of Science and T echno logy, Sh angh a i 2002 37, Ch ina; 2. Sh angh a i Baostee l Chem ica l Co. , L td. , Shangh a i 20 1900, Ch ina) A bstrac t: 4, 4 D ichlorom ethy l b ipheny lw as synthesized through chlorom ethy lation of biphenyl, starting w ith b iphen y l and p araform a ldehyde as raw m ater ia ls, zinc ch lo ride /H O as cata ly st in the presence o f hydrogen ch lo ride. T he factors 2 such as reaction temp erature and reaction tmi e in fluencing on reaction y ie ld and pur ity w ere discu ssed. A nd the mi pur ities in produc t w ere ana ly zed by GCM ass. K ey w ord s: b ipheny;l chlorom ethy lation; 4, 4 dich lo rom e thy l b ipheny l; p ara form a ldehyde 4, 4 ( 4, 4 b is ( ch lorom ethy l) 20 80 90 , 5 biphenyl, BCMBP ) BCMBP , , FP CBS X, , 1 ; 20 , 2 , BCMBP 3 6 20 60 , C IB