乙醇水蒸气重整制氢反应条件的优化.pdfVIP

Vol. 32 No. 9 ( ) 2006-09 Journal of E ast China University of Science an T echnology ( Natural Science E ition) 1081 : 1006-3080( 2006) 09-1081-05 1, 2 3 杨　宇 , 　马建新 ( 1. 华东理工大学工业催化研究所, 上海200237; 2. 中原工学院材料化工系, 郑州450007; 3. 同济大学新能 汽车工程中心, 上海200092) : 对不同反应条件下乙醇水蒸气重整反应系统平衡的物质分布进行了热力学计算。结果表 明: 低压有利于乙醇水蒸气重整主反应的进行; 在n( 水) ∶n( 乙醇) = 8 ∶1条件下, 温度越高乙醇的 转化率越高, 氢的含量也越高; 在 900 K 时, 水醇比越高越有利于乙醇水蒸气重整反应向正方向进 行。实验结果与热力学计算的产物分布曲线基本一致, 进 一步证明了热力学计算的正确性。 : 乙醇; 水蒸气重整; 最优化 : O643 : A Optimizing the Reaction Condition of Ethanol Steam Reforming YA N G Yu1, 2 , MA J ian-x in3 ( 1.I nstitute of I ndustrial Catalysis, E ast China University of Science and Technology , Shanghai 200237, China; 2.De artment of M ater ial and Chemical E ngineering , Zhongyuan Univ ersity of Technology , Zhengz hou 450007, China; 3. Clean Energy A utomotiv e E ngineering Center, T ongj i University , Shanghai 200092, China) : Abstract T he equilibrium substance composition of ethanol steam reforming system w as calculate by thermo ynamics an compare w ith measure ones. Effects of temperature, pressure an w ater/ ethanol molar ratio were also analyze w ith thermo ynamics theroy. T he results show that the ecrease of pre- ssure favore the steam reforming of ethanol in this system. T he conversion of ethanol an the content of , / hy rogen increase w ith the increasing of reaction temperature w hen water ethanol molar ratio is equal to 8 at 101. 325 kPa. At 900 K the higher w ater/ ethanol molar ratio the esire reacti