介孔碳材料.ppt

碳材料（部分）的微反应体系 姚月 110924 多孔材料 Porous carbon materials have been applied to gas separation, water purification, catalyst supports, and electrodes for electrochemical double layer capacitors and fuel cells. According to the International Union of Pure and Applied Chemistry (IUPAC) recommendation, porous carbon materials can be classified into three types based on their pore sizes: microporous 2 nm, 2 nmmeso-porous 50 nm, and macroporous 50 nm. 合成方法 介孔碳材料 Meso-porous carbon materials are very important for applications involving large molecules, such as adsorbents for dyes, catalyst supports for biomolecules, and electrodes for biosensors. 纳米微反应器 借助微通道反应器的特点进行的化学反应的改进 液相实验数据 Cnts 有可能阻碍了酸中心使得反应转化率明显降低； 引入TEOs凝胶，反应转化率较低，选择性40%左右，是在最近设计得到的固体催化剂中最高的。可能的原因是像文献里所说凝胶起到了微通道的效果。 固定床数据 * * LOGO 1 2 3 4 Contents background Meso-porous carbon materials microreactor 实验部分 Adv. Mater. 2006, 18, 2073–2094 J. AM. CHEM. SOC. 9 VOL. 131, NO. 12, 2009 4543 Chemical Engineering Science 66 (2011) 5366–5373 Applied Catalysis B: Environmental 102 (2011) 232–242 Adv. Synth. Catal. 2005, 347, 225– 230 Ureas b c a：氢气还原 b：催化剂的酸中心2倍 c：反应时间为2h Catal Lett (2009) 129:20–25 Meso-porous 交换4次后 浸渍法添加助剂Ce，Sn，Gr， Al ，Zn * *