纳米MoS3的制备研究.pdfVIP

纳米MoS3 的制备研究* 1,2 2 2 1 2 陈寅 ，肖清贵 ，徐红彬 ，郭奋 ,张懿 1 2 （北京化工大学，北京 100029； 中国科学院过程工程研究所，北京 100190） 摘要:本文以降低MoS3 产物平均粒径为目的,以四硫代钼酸铵和硫酸为原料,在带加热夹层的玻璃反应器中 制备MoS .分别通过正交实验和单因素实验考察了三个主要影响因素(所加入H SO 浓度,反应溶液熟化时 3 2 4 间及反应温度等)对产物平均粒径的影响.实验结果表明,反应温度对产物平均粒径的影响最大.利用冷场扫 描电子显微镜(SEM),X 射线衍射仪(XRD)和马尔文激光粒度仪对MoS3 前驱体产物进行表征,表明所得产物 为非晶态不规则晶体,且平均粒径在100nm-200nm 之间. 关键词:四硫代钼酸铵；非晶态；三硫化钼；纳米颗粒 中图分类号:TQ136.1+2 文献标志码:A Preparation of Nanostructured-MoS3 1,2 2 2 1 2 Chen Yin , Xiao Qinggui , Xu Hongbin , Guo Fen ,Zhang Yi 1 ( College of Chemical Engineering, Beijing University of Chemical Technology, Beijing, 100029, China; 2 Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Science, Beijing, 100190, China) Abstract ：MoS3 was prepared in a glass-material reaction kettle with heating jacket, using (NH ) MoS and sulfuric acid as raw materials. Three main factors (the concentration of raw 4 2 4 material, the ageing time of reaction solution and the reaction temperature) were investigated through orthogonal experiment and through single factor experiment, respectively. The experimental results show that the average particle size of products was most dependent on the reaction temperature. The MoS3 products were characterized by Scanning Electron Microscope (SEM), Powder X-ray diffraction (XRD) and Mastersizer 2000 Laser Particle Size An