Energies, Forces, and Bonds.ppt

Energies, Forces, and Bonds Dept. Phys., Tunghai Univ. 93學年度第二學期?生物物理 施奇廷 Interatomic Potentials for Strong Bonds Relation between potential energy and force: For central force (only depend on the distance): The interatomic force is attractive for long distance and repulsive for short distance (see Fig.3.1) Interaction Functional Forms of Strong Bonds 由前章所介紹的各種鍵結形式暗示我們，分子中原子間的交互作用可能也有好幾種形式（雖然都來自電磁交互作用）： Closed-shell repulsion (Born-Mayer function) Coulombic interaction potential Covalent interaction potential Morse potential function Closed-Shell Repulsion 1932, derived by Max Born and Josep