中国杉木炭化物中洋葱状富勒烯及金刚石晶格结构的观察.docVIP

中国杉木炭化物中洋葱状富勒烯及金刚石晶格结构的观察 黄 彪1 陈学榕1 廖益强1 唐兴平1 江茂生1 高尚愚2 （1.福建农林大学材料工程学院，福州350002； 2.南京林业大学化工学院，南京 210037） 摘 要：采用高分辨透射电子显微镜HUANG Biao 1，CHEN Xue-rong1，LIAO Yi-qiang1，TANG Xing-ping1， JIANG Mao-sheng1，GAO Shang-yu2 1. College of Material Engineering, Fujian Agriculture and Forestry University, Fuzhou, 350002, China 2. College of Chemical Engineering, Nanjing Forestry University, Nanjing, 210037, China ) Abstract: By means of HRTEM, the micro-pore, nano-structure and graphite-like micro-crystal in the Chinese fir thinnings charcoal are observed and studied in this paper. For the first time onion-like graphite particles (Fullerenes) structure and diamond structure are observed in the Chinese fir thinnings charcoal samples which is heated to 700℃. The experiments reveal the critical temperature point where the qualitative change of carbonized material occurs. The results show, microcrystal groups resulting from several hexagon carbon plane with larger crystal can be clearly observed in the Chinese fir thinnings charcoal samples, owe to the rising of temperature, microcrystal groups of this structure increase, its area widens, furthermore, its structures line up more neatly with clearer appearance. Apart from this, micro-pore appearance of carbonized material and features of graphite-like nano microcrystal can be clearly witnessed. Moreover, it can be observed that micro-pore, nano-structure and graphite-like micro-crystal greatly exist in carbonized samples, with its pore size at about 2nm~10nm, which are loosely distributed in carbonized materials. Keywords: Wood charcoal, Microporous structure, Onion-like graphite particles, Diamond structure 近年来木炭的新用途及作为新材料的研究开发十分活跃。木质炭化物的高效开发利用，对解决废弃物资源化、环保、生态环境等问题将起到十分积极的作用。从木炭开发制造出高机能性炭素材料，以及木炭在环境净化方面的应用等方面的研究与开发倍受关注。尽管在木材炭化理论方面很早就进行过不少研究，取得了一些成果，但随着先进的检测仪器与手段的日益更新，对木炭的研究实有必要更上一层楼[1-3]。 由石墨状微晶和无序碳所构成的多相物质决定着木质炭化物独特的结构。微晶的不规则排列形成了许多大小为10-10~10-8 m的孔隙，这些从微孔到大孔的各种孔隙构成了炭材料的微观世界，在炭材料的内表面上所进行的一切传质过程，就是借助这些孔隙系统而实现的。作为吸附剂的炭材料，由于其表面积大和