锂空气电池中催化剂行为地研究.pdfVIP

第30届全国化学与物理电源学术年会 锂空气电池中催化剂行为的研究 ∗ 马忠，原鲜霞 ，沙浩东，马紫峰 上海交通大学化学工程系，上海，200240 摘要：锂空（氧）气电池(Lithium Air Batteries)因其极高的能量密度（其理论能量密度高达 11140 Wh/kg，即使 将氧气的重量计算在内也有 3505 Wh/kg)，具备成为电动汽车动力电池的巨大应用潜力[1-3]。然而，由于充放电 过程中存在的过电势造成放电电压过低、充电电压过高，从而使得电池的能量效率较低[3]。催化剂可以有效降 低电化学过程中的极化现象，从而提高能量转换效率[4-5]。为此，本文采用Super P 作为碳源、聚四氟乙烯（PTFE） 作为粘结剂，着重考察了碳负载二氧化锰催化剂在不同倍率下对充放电过程中过电势的影响。同时，催化剂的 负载量对电势的影响也做了初步研究。 关键词：锂空气电池；催化剂；过电势 Study on the behavior of catalyst in lithium air batteries * Zhong Ma, Xianxia Yuan , Hao-Dong Sha, Zi-Feng Ma Department of Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240, China Abstract: Lithium air (oxygen) batteries are becoming a kind of significant promising energy storage and conversion technology for electric vehicles because of their ultrahigh energy density (11140Wh/kg excluding oxygen and 3505Wh/kg if oxygen included)[1-3]. However, at present, the poor round-trip efficiency (low discharge voltage and high charge voltage) caused by the large overpotential in discharge-charge process restricts their application [3]. The energy conversion efficiency could be improved by introducing catalyst which could reduce the electrochemical polarization [4-5]. Therefore, in this article, the overpotentials in discharge-charge process on carbon supported MnO2 catalyst at different rates were investigated. Besides, the influence of catalyst loading was also discussed. Keywords: Lithium air batteries; Catalyst; Overpotential Acknowledgements: The authors are grateful for the financial support of this work by the National Science Foundation of China , the STCSM of China (10JC1406900). References： [1] K. M. Abraham, Z. Jiang. J. El