农药多残留分析中QuEchERS方法介绍_胡西洲.pdfVIP

5 4 Vol.5 No.4 2006 8 Modern Agrochemicals Aug. 2006 QuEchERS 430064 QuEchERS 1% PSA Teflon GC/MS LC/MS TQ 450.263O 655.11 A 1671-5284(2006)04-0024-06 Introduce of Quick, Easy, Cheap, Effective, Rugged and Safe (QuEchERS) Approach for Determining Pesticide Residues HU Xi-zhou, CHENG Yun-bin, HU Ding-jin (Food Quality Inspection and Testing Center (Wuhan) Ministry of Agriculture, Wuhan 430064, China) Abstract: This chapter describes a simple, fast, and inexpensive method for the determination of pesticides in foods and potentially other matrices. The method, known as the quick, easy, cheap, effective, rugged, and safe (QuEchERS) method for pesticide residues involves the extraction of the sample with acetonitrile (MeCN) containing 1% acetic acid (Hac) and simultaneous liquid-liquid partitioning formed by adding anhydrous magnesium sulfate (MgSO4) plus sodium acetate (NaAc) following by a simple cleanup step known as dipersive solid-phase extraction (SPE). The QuEchERS method is carried out by shaking a Teflon centrifuge tube which contains 1mL of 1% Hac in MeCN plus 0.4g anh. MgSO4 and 0.1 g anh NaAc per sample. The tube is then centrifuged, and a partion of the extract is transferred to a tube containing 50 mg primary secondary amine (PSA) sorbent plus 150 mg anh. MgSO4 per mL extract (the dispersive-SPE cleanup step). Then, the extract is transferred to autosampler vials for concurrent analysis by GC/MS and LC/MS-MS. Estimation of the method’ stabili