SC-1997-701-酯交换制备环亚硫酸酯.pdfVIP

SYNTHETIC COMMUNICATIONS, 27(4), 701-707 (1997) PREPARATION OF CYCLIC SULFITES BY TRANSESTERIFICATION OF DIOLS AND DIISOPROPYL SULFITE Steven A. King,* Brenda Pipik,* David A. Conlon and M. Bhupathy Department of Process Resear, Merck Research Laboratories R80Y-355, P.O.Box 2000, Rahway, NJ 07065-0900,USA Abstract: Cyclic Sulfites of 1.2-, 1,3- and 14-diols canbe prepared in high yield by acid or base catalyzed transesterificationwith diisopropyl sulfite. Cyclic sulfites of 1.2- and 1.3- diols have s