多孔氧化铝模板在酸性和碱性介质中的腐蚀过程.pdfVIP

! 36 ! 材料导报:研究篇 2010 年3 月(下) 第24 卷第3期 * 程 亮, 田永涛, 智 钢,马姗姗, 吴黎红,冯 飞,贾河顺, 张迎九,李新建 ( , 450052) 将AAO 模板分别在体积 为1 9(约 15%( 质量分数)) 的 H PO 溶液和10% (质量分数)的 NaOH 3 4 溶液中进行蚀刻处理, 结果显示,AAO模板经过 一个扩孔过程, 最终孔间壁较薄部分被彻底蚀刻掉, 孔间壁较厚部分 留下形成氧化铝纳米线状结构在2 种蚀刻溶液中, NaOH 溶液对模板的蚀刻 H PO 溶液的快这些结果对于 3 4 AAO 扩孔氧化铝纳米结构的合成以及模板的去除具有 一定的指导意义 Chemical Etching Process of Anodic Aluminum Oxide Membranes in the Acid Solution and the Alkaline Solution CHENG Liang, TIAN Yongtao, ZHI Gang, A Shanshan, WU Lihong, FENG Fei, JIA Heshun, ZHANG Yingjiu, LI Xinjian ( Key Laboratory of aterial Physics inistry Education, Department of Physics, Zhengzhou University, Zhengzhou 450052) Abstract Chemical etching treatment of AAO template is important for the further application of AAO tem plate. The chemical etching is carried out by immersing AAO template in 1 9( V/ V , about 15wt%) H PO solution 3 4 and 10wt% NaOH solution respectively. Theresults demonstratethat thepores of AAO template are widened firstly, and the alumina nanowires are synthesized finally in etching process. In thetwo kinds of etching solution. Etching fas ter in NaOH solution than in H PO solution. The results is valuable in widening AAO template pores, synthesizing 3 4 the alumina nanostructures and removing the AAO template after assembly of materials. Key words anodic aluminum oxide(AAO) , porewidening, chemical etch