简单法制备具有可见光催化性的螺旋状N,S共掺TiO2.pdfVIP

Available online at Applied Catalysis B: Environmental 79 (2008) 72–80 /locate/apcatb Simple fabrication of twist-like helix N,S-codoped titania photocatalyst with visible-light response Jian-Hua Xu a, Jingxia Li a, Wei-Lin Dai a,*, Yong Cao a, Hexing Li b, Kangnian Fan a a Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433, PR China b Department of Chemistry, Shanghai Normal University, Shanghai 200234, PR China Received 20 April 2007; received in revised form 2 October 2007; accepted 8 October 2007 Available online 13 October 2007 Abstract Visible-light responsible N,S-codoped titania photocatalyst was fabricated by simple hydrolysis of titania tetrachloride using ammonia in the presence of glacial acetic acid and ammonium sulfate. The N,S-codoped titania materials were fabricated by a template-free route and demonstrated twist-like helix morphology. The morphology and microstructure characteristics of N,S-codoped titania photocatalysts were characterized by means of the N2 adsorption–desorption measurements, thermal gravimetric and differential thermal analysis (TG-DTA), transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), UV–visible diffuse reflectance spectra (DRS) and X-ray powder diffraction (XRD). The unique morphology of N,S- codoped titania materials and mesoporous micro