WFGD工艺典型脱硫添加剂应用探讨_杨磊.pdfVIP

23 3 Vol.23 No.3 2007 5 Power System Engineering May, 2007 1005-006X 2007 03-0004-04 WFGD WFGD DBA 3 SO2 WFGD DBA X701.3 A Explore the Application of Typical Addition Agent of Desulphurization in WFGD Techniques YANG Lei, LU Xiao-feng Abstract: Given the limestone wet FGD technology in the desulphurization market dominance, it mainly exposes three typical additions such as magnesium, DBA, formic acid, and talk about their action mechanism and industrial applications. Theory and practice proves that the addition agent of desulphurization can enhance the efficiency of sulfur removal and utilization of limestone, reduce the risk of plug and dirty, save the fixing and operational cost. Key words: limestone; WFGD; addition agent; magnesium; DBA; formic acid SO2 pH SO [3] 2 2 SO2 3 DBA Dibasic Acids / pH Adipic Acid / 3 WFGD 2.1 1 FGD SO2 SO32- HSO3- SO32- SO2 SO2 WFGD MgSO [4] 3 SO2 MgSO4 Mg2++SO42- 3 - 2- HCO SO SO 2+ 2- 3 3 2 Mg +SO3 MgSO3 4 [12] 4 MgSO3 SO32- SO 2-+ SO +H O2HSO - 1 3 2 2 3 HCO -+ SO CO +HSO - 2 SO +SO 2-+H O2 HSO - 5 3 2 2 3 2 3 2 3 HCO3-SO32-CaCO3 CaSO3 SO2 CaSO ·1/2H O 3 2 Ca2++ SO 2-+1/2H OCaSO ·1/2H O 6 3 2 3 2 O2 SO42-3 SO42-Ca2+ Ca2++ SO 2-+2H OCaSO ·2H O 7 : 2006-10-19 4 2 4 2 1981- 400030 MgSO3 3 WFGD 5 2- + 2- - SO3 SO2 H +A HA 16 SO H+ - + HA H A 17 2 2 78% 83%[5] Harrison Dravo Lime Company ThioClear Mg OH 2 1 [10] 98% Mg OH 2 98%[6,7] 1991 [11] 1400 MW Zimmer BW MEL 45% 96%[8] KHI [8] 1 1 [8] 1 - Zimmer Saijho Matsuura 1991 1984 1990 /MW 1400 250 1000 FGD /MW 250 250 500 SO /mg ·m-3 2500 930 700 2 /% 96 94 95 pH 6.2 5.5 - L/G/L ·m-3 3 4 15 /Pa 830 3560 900 pH 2 DBA pH 6.5 2 DBA pH DBA pH 2.2 DBA / R pH DBA HOOC- CH -COOH DBA 3 HOOC-R-COOH pH 2 n n 2 n 3 pH 4 n 4 DBA HOOC-R-COO- pH DBA pH 6 SO2 SO2 -OOC-R-COO- + DBA SO2 DBA H - - + - 20 OOC- CH -COO +H HOOC- CH -COO 8 2 n 2 n - + 1986 Mobley HOOC- CH -COO +H HOOC- CH –COOH 9 2 n 2 n