正文完整版氧化铝.docVIP

聚酰亚胺Al2O3杂化薄膜的制备与表征 摘 要 本文以均苯四甲酸二酐（PMDA）和4,4’-二氨基二苯醚（ODA）为单体，以N,N’-二甲基二苯醚（DMAc）为溶剂，制备聚酰胺酸溶液。在此过程中，采用原位聚合法在酰胺酸溶液中加入氧化铝（Al2O3），通过热亚胺化处理制备得到氧化铝/聚酰亚胺（Al2O3/PI）杂化薄膜。用傅立叶变换衰减透射射红外光谱ATR/FTIR）、静态热机械分析TMA）、力学性能测试等手段对PI/ Al2O3杂化薄膜结构和性能进行表征。 红外分析表明，杂化薄膜热亚胺化完全，杂化反应充分进行，并且Al2O3和PI基体之间形成键接；TMA分析表明，PI / Al2O3杂化薄膜的热膨胀系数随氧化铝含量的增加而减小；常温拉伸性能测试表明，随着Al2O3量的增加，PI杂化薄膜弹性模量逐渐增大，而拉伸强度和断裂伸长率呈下降趋势；玻璃化转变温度测试表明，杂化Al2O3之后的玻璃化温度不是很明显；热重分析表明，引入一定量的Al2O3，薄膜的热分解温度降低。而含有10 wt%氧化铝的杂化薄膜各项性能都表现出相对优良的性能。 关键词：热固性聚酰亚胺 薄膜 氧化铝 杂化 原位聚合法 Characterization and Preparation of Alumina/ Polyimide Hybrid Films Abstract This paper use 4,4-diaminodiphenyl ether (ODA) polymerized with pyromellitic acid dianhydride (PMDA) in N,N-dimethylacetamide(DMAc) produce PI, and polyimide-alumina hybrid films were prepared by the situ polymerization reaction starting from Al2O3 in the solution of polyamic acid and Al2O3 inorganic nano-particles in polyimide, followed by thermal imidization. The hybrid films were characterized by ATR/FTIR, Thermal Mechanical Analysis (TMA), and Mechanical Property Test. The result of ATR/FTIR test showed that the polyamic acid films converted into polyimide films absolutely, and Al2O3 was connected with PI by chemical bond The coefficient of thermal expansion of the Al2O3/PI hybrid films decreased with increasing the content of the Al2O3. The modulus of the hybrid films increased, however, the elongation at fracture and the tensile strength decreased. Glass transition temperature tests showed that the addition of the Al2O3 increasing content of the hybrid films made little effect on temperature. TG analysis showed that the introduction of a certain amount of Al2O3, help to reduce the film of pyrolysis temperature. However, with the 10 percent of the alumina, the hybrid films have show the good performance relatively. Key Words: Thermosetting polyimide; Film; Alumina; Hybrid; Situ polymerization目 录 摘 要 I Abstract II 第一章 文献综述 1 1.1 聚酰亚胺 1 1.1.1 概述 1 1.1.2 分类 1 1.1.3 性能 2 1.1.4 应用 3 1.1.5 聚酰亚胺改性分析