活性自由基聚合,RAFT.ppt

RAFT 试剂的合成： RAFT 试剂的合成：部分已经商品化！ 嵌段聚合物的制备： 大致顺序：甲基丙烯酸酯基 苯乙烯基， 丙烯酸酯基。 星形聚合物的制备： 聚合物RAFT 端基的脱除与转换： 聚合物RAFT 端基的脱除与转换： With an excess of radicals 表明RAFT聚合中可控性要好引发剂用量一定要尽可能少 聚合物RAFT 端基的脱除与转换： 聚合物RAFT 端基的脱除与转换： Switchable RAFT AGENT: 适用高活性和低活性单体！ J. AM. CHEM. SOC. 2009, 131, 6914–6915 RAFT AGENT的突破： Switchable RAFT AGENT: J. AM. CHEM. SOC. 2009, 131, 6914–6915 新的想法： Recently, it has been suggested that the control exerted by certain thioketones X S; A-R, Z alkyl or aryl over free radical polymerizations may proceed via such a mechanism Chem. Commun. Camb. U K 2006, 835–837. H. Chaffey-Millar, E. I. Izgorodina, C. Barner-Kowollik, M. L. Coote, J. Chem. Theor. Comput. 2006, 2, 1632–1645. T. Junkers, M. H. Stenzel, T. P. Davis, C. Barner-Kowollik, Macromol. Rapid Commun. 2007, 28, 746–753. BYK-Chemie： In 2007, BYK announced the commercialization of two polymer additives for coatings produced by a nondisclosed CRP process. DISPERBYK-2010 is a wetting and dispersing additive for aqueous systems. CRP的工业化： Dupont has always been extremely active in RD to propose and test novel CRP technologies, most of the time in collaboration with the Australian Commonwealth Scientific and Research Organization CSIRO . The company proposes a portfolio of licensable intellectual property including various addition-fragmentation transfer agents and catalytic chain transfer processes. CRP的工业化： The NMP process has gained much maturity since TEMPO was originally used as a moderator for radical polymerization by Dupont and Xerox. Ciba has developed a number of nitroxide regulators NORs , including special open chain NORs, piperazinone and piperidine-type NORs, and 7-ring heterocyclic NORs, One of the first commercial successes of NMP belong to Ciba now part of BASF through its EFKA additives subsidiary. CRP的工业化： CRP的工业化： Kaneka announced that it currently has a large pilot unit producing commercial samples Fig. and is constructing a full-scale plant to produce reactive telechelic ma