三氟化硼乙醚中联苯电聚合.pdfVIP

第十二届全国有机分子电化学与工业学术会议论文集 三氟化硼乙醚中联苯的电聚合 周靓洁，聂广明，张书圣* (青岛科技大学化学与分子工程学院，山东 青岛 266042) 摘要：导电聚合物的电合成主要是在有机溶剂或水溶液中进行。在这些介质 中联苯由于氧化电位高所得到的聚对苯性能较差。三氟化硼乙醚(BFEE)溶液能够 有效降低系列芳香族单体的氧化电位并获得了高性能的聚合物膜。在纯三氟化硼 乙醚中通过直接氧化联苯(biphenyl)合成了高性能的聚对苯膜。该体系中联苯的 氧化电位为 1.40 V vs. SCE，这比在乙腈(ACN)+0.1 mol L-1 四氟化硼四丁基铵 (TBATFB) 中的要低(2.11V vs. SCE)。在三氟化硼乙醚中获得的聚对苯膜表现出了 -1 -1 较好的电化学性质，其电导率为10 S cm ，这表明三氟化硼乙醚体系比乙腈体 系更有利于聚对苯膜的合成。结构研究表明联苯的聚合发生在 4 ，4 ’位。制备 的聚对苯膜能部分溶于丙酮、乙腈、四氢呋喃等。荧光光谱研究表明获得的聚对 苯是良好的蓝色荧光物质。 关键词：导电聚合物；电合成；聚对苯；三氟化硼乙醚 中图分类号: O632.7 文献标识码: A 文章编号: Electrochemical polymerization of biphenyl in boron trifluoride diethyl etherare ZHOU Liangjie ，NIE Guangming ，ZHANG Shusheng* (Key Laboratory of Eco-chemical Engineering, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, shandong PR China) Abstract: The electrochemical syntheses of conducting polymers were usually preformed in neutral organic solvents or in aqueous solution. The oxidation potentials of many aromatic monomers were decreased in boron trifluoride diethyl etherate (BFEE) and high-quality polymer films were obtained. High quality polybiphenyl films were synthesized electrochemically by direct oxidation of biphenyl in pure BFEE. The oxidation potential of biphenyl in this medium is measured to be -1 only 1.40 V vs. SCE, which is lower than that determined in acetonitrile + 0.1 mol L Bu NBF 4 4 (2.11 V vs. SCE). The polybiphenyl films obtained from th