胡萝卜中滴滴涕对人体生物有效性影响因素的体外研究.pdfVIP

28 2 Vol. 28, No. 2 2009 3 ENV IRONMENTAL CHEM ISTRY M arch 2009 * 1 1* * 1 1 1 陆 敏 余应新 张东平 张 帆 韩姝媛 2 1, 3 1, 3 吴明红 盛国英 傅家谟 ( 1 , , 200072; 2 , , 200444; 3 , , , , 510640) , , p, p DDT, p, p DDDp, p DDE. , DDTs , ; , p, p DDE, p, p DDD p, p DDT , 1272% , 1271% , 1199% 4714% , 4116% , 4629% . , p, p DDT, p, p DDD p, p DDE , , . , DDTs, , , , , , ( in vivo) ( in vitro) [ 1] . [ 2] , , . , , , , . DDTs(p, p DDT, p, p DDDp, p DDE), DDTs, . 1 11 , , , 80, p, p DDT, p, p DDDp, p DDE ( Supelco) , , , 8h, DDTs. 1L 1g 2g1g3g04g 3g1g4g 05g L. - 1 - 1 01mol l HCl, 009g700FIPU g . 200m l 25m l pH 30 ! 01. 1L 125g NaHCO , 60g 09g. 3 12 [ 3] 40m l, 12m l, , 37∀ 1h. , 7000# g 10m in, . 2008 4 30 * ( 06A 064) ( S3019) ( 2008CB18205) * * , yuyingx in@ staffshueducn 2 : 221 1h 6m l ( pH 70 ! 01), , 37∀ 4h, . 13 , , . DDT s ( PCB209), ( 120m l, 3), 10m lH SO (H SO , 2 4 2 4 ), , 1m l, . : 12cm ( 3% )6cm ( 3% ) 1cm . 20m l, 60m l∃ ( 1∃1, V/V) , 05m,l 2m l, , ( PCNB) , 4∀ GC /ECD. 14 100m l, PCB209, 20m l, 40m l∃ ( 1∃3, V/V) , 10m l , 20m l∃ ( 1∃3, V/V) 2. , 05m,l 30m l, 10m lH SO, . 2 4 15 GC/ECD 63 A lgient 6890N ECD N i, DB5MS ( 30m # 032mm # 025m )