CO在稀土复合吸附剂上吸附特性的研究.pdfVIP

第1期 　 居沈贵等: CO 在稀土复合吸附剂上吸附特性的研究　　 　2　9 CO ( 210009) : CO , Lang- muire , , :CO 0 , 1 , , C CO , , sized from methanol with carbon monoxide 1Ugo Ramano Rentato Tesel Mareello Massl, , and oxygen over a cupric chloride or cuprous Maurl, et al ., Ind. ng.Chem.Prod.Res. Dev., chloride catalyst A study is performed on. 1980, 19:396403 effects of the amount of catalyst, oxygen 2Jeaaup P J US, 4 600 408( 1986) concentration, reaction pressure, and nitro- 3, , . , 1983, 8 gen donor ligands on carbonylation. T he re- ( 3) : 1 sults show that the catalytic activity and se- 4 , , , . , lectivity of cuprous chloride to DMC are 1985, ( 6) : 2 5, , . , 1989, ( 10) : 1 higher than those of cupric chloride When. 6. , 1997, ( 26) : 5 the quantities of cupric and cuprous chlorides 1.0 10- 1 / 3 4. are lifted to g ml CH OH and - 2 Study of the copper-based cataly sts f or 0 10 g/ ml CH3OH respectively, further oxidati ve carbonyl ation of methanol to increment has little influence on the forma- di methyl carbonate tion rate of DMC. When a mixed gas with an oxygen content over