蓄冷新工质——四丁基氯化铵水合物的蓄冷特性实验探究.pdfVIP

蓄冷新工质——四丁基氯化铵水合物的蓄冷特性 实验研究 谢应明* 魏晶晶 刘道平 时竞竞 刘妮 祁影霞 上海理工大学能源与动力工程学院制冷技术研究所 上海 200093 摘 要：探讨了一种新型季铵盐——四丁基氯化铵的水合物作为蓄冷工质的可行性，对其蓄 冷特性进行了实验研究：研究了溶液浓度，循环次数，及添加成核剂硼砂对四丁基氯化铵水 合物的生长特性的影响。实验结果表明：浓度为 40%的 TBAC 溶液相变过程相对稳定，更 TBAC 2 适合空调蓄冷工况；添加成核剂硼砂使 溶液的相变温度降低了 ℃，结晶过冷度减小 2 ℃；经过多次重复水合反应后，溶液在结晶过程中的过冷度减小了 1.5℃，相变温度无变化。 利用 DSC 测试得到四丁基氯化铵水合物相变温度为 10.41℃，相变潜热为 197.707J/g。 关键词：水合物 蓄冷 四丁基氯化铵 Experimental Study On Novel Cold Storage Medium- Tetra Butyl Ammonium Chloride Hydrate Yingming Xie, Jingjing Wei, Daoping Liu, Jianjian Shi, Ni Liu Yingxia Qi Institute of Refrigeration Technology, School of Energy and Power Engineering, University of Shanghai for Science and Technology, Shanghai, 200093 Abstract: A novel quaternary ammonium salt—Tetra butyl Ammonium Chloride (TBAC) is chosen to generate hydrate for cool storage, the influence of solution concentration, cycle time, and borax as nucleation agent on the hydrates formation characteristics are studied. Result shown that the solution with mass concentration of 40% has more stable phase transition process, which is more suitable for air-conditioning cold storage system; Adding some nucleating agent such as borax in appropriate concentration to TBAC solution could decrease the phase transition temperature 2 ℃, and the super-cooling degree of crystallization could be decreased 2℃. After cycle reaction repeat for some times, the super-cooling degree is decreased 1.5 ℃, without any change of phase transition temperature. The DSC test has shown that the Tetra butyl Ammonium Chloride hydrate takes phase transition under the temperature of 10.41 ℃, with the latent heat of 197.707J/g. Keywords: Hydrate, Co