2A12铝合金表面双-(γ-三乙氧基硅丙基)四硫化物薄膜的特性.pdfVIP

理化学学报(Wuli Huaxue Xuebao) August A cta Phys. Chim. Sin., 2006, 22(8) ：1025 1029 1025 [Note] 2A12 T6 铝合金表面双( 三乙氧基硅丙基)四硫化物薄膜的特性 明安 谢 玄 戚海英 张新明 李慧中 杨 汐 (中南大学材料科学与工程学院, 长沙 410083) 摘要 采用傅立叶变换红外光谱分析了2A12鄄T6 铝合金表面自组装双鄄( 鄄三乙氧基硅丙基) 四硫化物硅烷偶联 剂(SCA)薄膜结构特征, 并采用电化学极化曲线评价了薄膜的耐蚀性能. 结果表明, 铝材表面自然晾干, SCA 薄 膜分子之间主要通过氢键连接, 腐蚀电 密度减小1 个数量级以上. 120 益的加热处理促进铝板表面通过SiOSi 链接而形成SCA 网状薄膜结构, 并通过在界面上形成SiOAl 界面相结构而与铝板表面牢固连接, 腐蚀电流密度 降低2 个数量级以上. SCA 乙醇溶液浸泡处理10 min 比浸泡2 s 1 min 的铝板表面SCA 薄膜内氢键缔合羟基 要多. 关键词： 铝合金, 双鄄( 鄄三乙氧基硅丙基) 四硫化 , 傅立叶变换红外光谱, 薄膜, 腐蚀 中图分类号： O647 Characterization of Self assembled Bis [triethoxysilylpropyl] tetrasulfide Silane Films on Surface of 2A12 T6 Aluminum Alloy CHEN, Ming鄄An XIE, Xuan QI, Hai鄄Ying ZHANG, Xin鄄Ming LI, Hui鄄Zhong YANG, Xi (School of Materials Science and Engineering, Central South University, Changsha 410083, P. R. China) Abstract Bis鄄[triethoxysilylpropyl] tetrasulfide silane films were self鄄assembled on surface of 2A12鄄T6 aluminum alloy for corrosion protection. The structure of the formed silane films was investigated by using Fourier transform infra鄄 red (FTIR) spectroscopy, and the corrosion performance of the film was evaluated by electrochemical potentiodynamic polarization tests in 3.5% NaCl solution. Compared to the untreated case, both the cathodic and anodic reactions of Al 2A12鄄T6 treated with the silane films are inhibited obviously. For the film on the surface of Al