可溶性共聚聚酰亚胺的研究.pdfVIP

18 : 2010, 43 4 1 1 1 1, 2 1,2 颜善银 , 黄明富 , 陈 川 , 徐祖顺 , 易昌凤 1. , 430062; 2. , 430062 : 2, 2- [ 4- 4- ] BAPP 4, 4- ODA , 3, 3, 4, 4 - ODPA , N, N- DMF , , FT - IR , : - 1 - 1 - 1 1780 cm 1 720 cm 725 cm D CT GA : , , , 500 , 800 56. 1%; 114. 6 MPa 2. 58 GPa12. 2%0. 89% :; ; :T M215;O631. 5; T B324; T Q323. 7 :A : 1009- 9239 2010 04- 0018- 05 S nthesis of Soluble Co ol imide Based y p y on BAPP- ODA- ODPA 1 1 1 1, 2 1, 2 YAN Shan- in , HUANG Min - fu , CHEN Chuan , XU Zu- shun , YI Chan - f en y g g g 1.Facult o M ater ial Science and En ineer in , H ubei Universit , Wuhan 4300 2, China; y f g g y 2.M inistry of Education K ey L abr otory f or the Green Pr ep aration and App lication of Funtional M aterials, Wuhan 4300 2, China Abstract: A so ub e copo yimide was synthesized via the convent iona two_st ep therma or chemica imidizat ion rocess b usin 2, 2_bis [ 4_ 4_amino henox hen ] ro ane BAPP and 4, 4 p y g p y p y p p _diaminodi hen ether ODA as the diamine monomer, 4, 4_ox di htha ic dianh dr ide ODPA as p y y p y the dianh dride monomer in dimeth f or mamide DM F . T he structur e of the co o imide was char y y p y acter ized by FT IR. T he FT IR t est indicates that the copo yimide exhibit s char acteristic p eaks of - 1 - 1 - 1 po y imides around 1 780 cm , 1 720 cm and 725 cm . T he pr oper ties of the copo yimide wer e measur ed by so ubi ity tests, DSC, T GA, tensi e t ests and water absorbency t est s. T he resu ting co o imide is so ub e in common or anic so vent s. It has ood therma st abi it , with initia de p y g g y com osit ion tem erature hi her than 500 , and shows 56. 1% of residue at 800 under nitro en p p g g atmos here. T he co o imide fi m shows 114. 6 M Pa of tensi e stren th, 2. 58 GPa of t ensi e modu p p y g us, 12. 2% of e on at ion at break and 0. 89% of wat er absorbenc . g y Ke words: cop