Synthesis and Characterization of Waterborne Epoxy Curing Agent Modified by Silane.pdfVIP

维普资讯 Chin．J．Chem．Eng．，15(6)899—905(2007) Synthesisand Characterization ofW aterborneEpoxyCuringAgent M odifiedbySilane LUGuangqi(卢光岐)，SUNJianzhong(~J、建中)andZHOUQiyun()~其云) StateKeyLaboratoryofChemicalEngineering，DepartmentofChemicalandBiochemicalEngineering，Zhejiang University，Hangzhou310027，China Abstract A novelwaterborne epoxy curing agentwasprepared using 3-glycidoxypropyltrimethoxysilane (GPTMS)asaterminationagentofadduct，whichwassynthesizedbytriethylenetetramine(TETA)andliquidep— oxyresinrE～511．Theeffectsofthereactiontemperatureandtimeonthesynthesisprocesswereinvestigatedex— perimentally．Theparticlesizeandthedistlibutionofwaterdispersionofthecuringagentweremeasuredbydy— nma iclightscatteringrDLS)．Th estructureofhteproductswaschraacterizedbyFouriertransofrm infrraedspec— trometer(FTIR)and H—nucleramagneticresonna ce(HNMR)．Thepropertiesofthesynthesizedcuringagentand theepoxyresinfilm curedbyitwerealsomeasured．Theresultsshowedthattheappropriatetemperatureforthe synthesisofadductwasat65～75℃ andthereactiontimewas4— 5h．na dthatthesuitablereactiontemperatureof curingagentsynthesiswas75～ 85℃ andthereactiontimewas3— 4h．WhenthemassratiosofGPTMSandacetic acidwere3％一 5％ and5％一 10％ respectively．thehradness．waterresistanceandadhesionofthecuredfilm were improvedsignificantly． Keywords waterborneepoxycuringagent，silane，modification 1 INTRoDUCTIoN been evaluated in both one．．pack and two．．pack sys．． Epoxy resinsarewidely applied in protective temsby Cheneta1．f101．A novelamineterminated coatings．structuraladhesives，andelectronicindustry elastomericsiloxanemodifier(siloxaneamide．SA1 becauseoftheirheat，solvent，moistureandchemical forsolventepoxy networkswassynthesized andthe resistance，goodmechanicalandelectricalproperties，