高强度多孔透波Si3N4陶瓷的制备和性能研究.pdfVIP

R31 高强度多孔透波 Si N 陶瓷的制备及性能研究 3 4 1,2 2* 2 1 尉磊 汪长安 魏乔苑 孙加林 (1.北京科技大学材料科学与工程学院，无机非金属材料系，北京 100083； 2.清华大学材料科学与工程系，新型陶瓷与精细工艺国家重点实验室， 北京 100084) 摘要：本文以氮化硅为原料，以叔丁醇为溶剂，采用凝胶注模成型工艺，在无压烧结温度为 1780 ℃、保温时间为 1.5 h、流动氮气气氛下，成功的制备出具有高强度和高气孔率的多孔氮 化硅陶瓷透波材料。通过对材料的密度、孔隙率、压缩强度和介电性能测试及显微组织观察， 系统分析了固相含量对材料性能和组织的影响。研究结果表明：随着固相含量的提高，孔隙率 与介电性能呈下降趋势而抗压强度呈上升趋势。当固相体积分数为 15%时，制备出孔隙率达到 63.1%、抗压强度达到 329.4±1.6 MPa、介电常数在 10 MHz 频率下达到 3.99 的高性能多孔透波 氮化硅陶瓷。 关键词：氮化硅；多孔陶瓷；透波；性能 Preparation and properties of high strength wave-transparent porous Si N ceramics 3 4 1,2 2 2 1 YU Lei , WANG Chang-An , WEI Qiaoyuan , SUN Jialin ( 1. Department of Inorganic Nonmetallic Materials, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083, China ； 2. State Key Lab of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China) Abstract: In this paper, high strength and high porosity wave-transparent porous Si3N4 ceramics were prepared by tert-butyl alcohol (TBA)-based gel-casting process and pressureless sintering at 1780 ℃ for 1.5 h in flow nitrogen. The properties of density, porosity, compressive strength and dielectric constant and loss were researched and the microstructure was observed. The influence of solid loading in initial slurry on the properties of wave-transparent porous Si N ceramics was investigated also. The results 3 4 showed that the p