全像光栅在液晶及高分子材料的研究.ppt

Experiment I: Temperature and polarization dependence of transient gratings in azo-dye- doped liquid crystals II: The enhancement of diffraction in liquid crystals on dye-doped polymer films Introduction 液晶的正單光軸晶體光學雙折射性 Dielectric anisotropy of the liquid crystals 5CB液晶折射率隨溫度的變化 5CB液晶方位秩序隨溫度的變化 Dye-Induced Torque in Dye-Doped Nematics Janossy model (“Positive” torque ) Gibbons model (“Negative” torque) Photoisomerization Effect Induced LC Reorientation Results and discussion Conclusions of Experiment Ⅰ-1 1.產生瞬態光柵的機制有兩個。 2.寫入光的偏振平行於導軸時的一階繞射訊號較大。 3. 一階繞射訊號衰減時間會隨溫度的上升而增加。 Experiment II: The enhancement of diffraction in liquid crystals on dye-doped polymer films DDPF 及DDPF/5CB 薄膜的SRG Conclusions of Experiment II: 1. 寫入光源能量足夠大時(4.5mJ/cm2)，作用於DR1- PMMA薄膜產生的繞射訊號沒有鬆弛現象。 2. 訊號凹陷(dip) 是由於光散射的結果。 3. DR1-PMMA/5CB樣品所產生的表面起伏光柵(SRG)較深。 * * 全像光柵在液晶及高分子材料的研究 黃宣瑜 國立中山大學物理系 非線性光學實驗室 奈米科技研發中心 博士後研究 主要特徵： 1.分子長軸方向有序 2.重心位置無序 (director axis) 向列相(nematic)液晶分子的排列圖及方位秩序 S(θ) = 3cos2θ-1 e n o n e n o n ) ( q eff n q ) ( q eff n q E LC Δε=ε∥-ε⊥ 若Δε0 uE minimum 若Δε0 uE minimum Excited-state of dye molecules Ground-state of dye molecules n n E Upon absorbing light, azo-dye molecules may undergo a photo-induced conformational change, which is called photoisomerization effect. Laser induced grating q l p I1 I2 L x I x z y q 1 k r 2 k r x z y q x z y q k r k r k r k r x z y q I1=I2=I0 Imax=4I0 Imin=0 The definition of the first order diffraction efficiency: Λ Experimental setup MIRROR He-Ne LASER MIRROR BEAM SPLITTER SAMPLE APERTURE FILTER DETECTOR OSCILLOSCOPE POLARIZER Nd: YAG LASER Experiment I-1: (Pump , Probe) A∥/A⊥=4.5 ( ⊥, ∥) (⊥, ⊥) (∥, ∥) (∥, ⊥) (⊥,∥) (Pump, Probe) 31℃ 30.5℃ 30℃ 29.5℃ 31.5℃ (Pump, Probe) no ne nav nav ~ 0.112 ~ 0.058 29.5~31.0℃ n 31.5℃~32.5℃ 激發光源偏振垂直導軸 nav nav 激發光源偏振平行導軸 n DR1-PMMA薄膜在不同的pulse energy作用下之一階繞射效率 27℃ 34℃ 32℃ 36℃ DDPF DDPF/5CB