水性环氧_苯丙杂化乳液配方研究.pdfVIP

K2水性环氧_苯丙杂化乳液的配方研究 郭文录 朱华伟张莉 （江苏科技大学 材料科学与工程学院，江苏 镇江 212003） / 摘要：通过杂化乳液聚合方法，制备环氧树脂 丙烯酸树脂的复合胶乳乳液，工艺简单，不用有机共溶剂， 环保高效。本文采用核壳乳液聚合工艺，通过正交实验法对配方中环氧树脂、乳化剂、引发剂、功能性单 体的用量进行综合考虑，有效解决了实验因素的相互影响性，制成一种稳定性良好的环氧改性苯丙乳液。 研究结果表明，配方为：N-MA用量为1%，MAA用量为2% ，乳化剂的用量为3%，环氧树脂用量为6%， 引发剂用量为0.6% 。利用红外光谱仪对改性苯丙乳液进行了表征，发现在915cm-1 出现环氧基吸收峰，1251 -1 cm 出现苯醚吸收峰，证实了接枝产物的存在。 关键词：正交试验；环氧树脂; 苯丙乳液；改性 Study on Formulation for Epoxy-Styrene Acrylic Hybrid Emulsion GUO Wenlu，ZHU Huawei ，ZHANG Li (School of Material Science and Engineering ,Jiangsu University of Science and Technology ,Zhenjiang 212003 ,China) Abstract: The epoxy acrylate emulsion was made by hybrid emulsion polymerization. This method has simple technology, none solvent and friend to the environment. The emulsion of styrene-acrylic with epoxy resin was prepared by use of core-shell emulsion polymerization technology. The factors such as amount of epoxy resin ，amount of emulsifier ,amount of initiator, amount of functional monomer, were investigated by the orthogonal experiment. The relation of interactional factors was confirmed, and one kind of steady emulsion was made. The best formulation condition of modified emulsion could be obtained when the contents of N-MA was 3%, the contents of MAA was 1%, the content of emulsifier was 3%, the content of epoxy resin was 6%, the content of initiator was 3%. The structure of modified styrene-acrylic emulsion was characterized by FTIR, the peaks at 915cm-1 and 1251cm-1 correspond respectively to the motion of epoxy group and phenylate, so the graft polymer was confirmed. Keywords: orthogonal test, epoxy resin, styrene-acrylic emulsion, modification 作